High charge-carrier mobility in an amorphous hexaazatrinaphthylene derivative

被引:93
作者
Kaafarani, BR
Kondo, T
Yu, JS
Zhang, Q
Dattilo, D
Risko, C
Jones, SC
Barlow, S
Domercq, B
Amy, F
Kahn, A
Brédas, JL
Kippelen, B [1 ]
Marder, SR
机构
[1] Georgia Inst Technol, COPE, Sch Chem & Biochem, Atlanta, GA 30332 USA
[2] Georgia Inst Technol, Sch Elect & Comp Engn, Atlanta, GA 30332 USA
[3] Univ Arizona, Dept Chem, Tucson, AZ 85721 USA
[4] Princeton Univ, Dept Elect Engn, Princeton, NJ 08544 USA
关键词
D O I
10.1021/ja0553147
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An isomeric mixture of a tris(pentafluorobenzyl ester) derivative of hexaazatrinaphthylene forms stable amorphous films with an effective charge-carrier mobility of 0.02 cm2/Vs, while the pure 2,8,15-isomer exhibits widely differing morphologies and carrier mobilities (0.001-0.07 cm2/Vs), depending critically on the processing conditions. Copyright © 2005 American Chemical Society.
引用
收藏
页码:16358 / 16359
页数:2
相关论文
共 17 条
[1]   Electric-field and temperature dependence of the hole mobility in poly(p-phenylene vinylene) [J].
Blom, PWM ;
deJong, MJM ;
vanMunster, MG .
PHYSICAL REVIEW B, 1997, 55 (02) :R656-R659
[2]  
Bock H, 2002, CHEMPHYSCHEM, V3, P532, DOI 10.1002/1439-7641(20020617)3:6<532::AID-CPHC532>3.0.CO
[3]  
2-M
[4]   Space-charge limited conduction with traps in poly(phenylene vinylene) light emitting diodes [J].
Campbell, AJ ;
Bradley, DDC ;
Lidzey, DG .
JOURNAL OF APPLIED PHYSICS, 1997, 82 (12) :6326-6342
[5]   Electronic delocalization in discotic liquid crystals:: A joint experimental and theoretical study [J].
Crispin, X ;
Cornil, A ;
Friedlein, R ;
Okudaira, KK ;
Lemaur, V ;
Crispin, A ;
Kestemont, G ;
Lehmann, M ;
Fahlman, M ;
Lazzaroni, R ;
Geerts, Y ;
Wendin, G ;
Ueno, N ;
Brédas, JL ;
Salaneck, WR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (38) :11889-11899
[6]   High charge-carrier mobility in π-deficient discotic mesogens:: Design and structure-property relationship [J].
Lehmann, M ;
Kestemont, G ;
Aspe, RG ;
Buess-Herman, C ;
Koch, MHJ ;
Debije, MG ;
Piris, J ;
de Haas, MP ;
Warman, JM ;
Watson, MD ;
Lemaur, V ;
Cornil, J ;
Geerts, YH ;
Gearba, R ;
Ivanov, DA .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (11) :3349-3362
[7]   Charge transport properties in discotic liquid crystals:: A quantum-chemical insight into structure-property relationships [J].
Lemaur, V ;
Da Silva Filho, DA ;
Coropceanu, V ;
Lehmann, M ;
Geerts, Y ;
Piris, J ;
Debije, MG ;
Van de Craats, AM ;
Senthilkumar, K ;
Siebbeles, LDA ;
Warman, JM ;
Brédas, JL ;
Cornil, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (10) :3271-3279
[8]   Charge transport properties of tris(8-hydroxyquinolinato)aluminum(III): Why it is an electron transporter [J].
Lin, BC ;
Cheng, CP ;
You, ZQ ;
Hsu, CP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (01) :66-67
[9]   Density functional theory study of the geometric structure and energetics of triphenylamine-based hole-transporting molecules [J].
Malagoli, M ;
Brédas, JL .
CHEMICAL PHYSICS LETTERS, 2000, 327 (1-2) :13-17
[10]   Electron transport in a methanofullerene [J].
Mihailetchi, VD ;
van Duren, JKJ ;
Blom, PWM ;
Hummelen, JC ;
Janssen, RAJ ;
Kroon, JM ;
Rispens, MT ;
Verhees, WJH ;
Wienk, MM .
ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (01) :43-46