Assembly modes in the solid state structure of the complexes of melamine mono-cations with para-calix[4]arene sulfonic acid and calix[4]arene dihydroxyphosphonic acid

被引:17
|
作者
Lazar, AN
Danylyuk, O
Suwinska, K
Coleman, AW
机构
[1] CNRS, Inst Biol & Chim Prot, UMR 5086, F-69367 Lyon 07, France
[2] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
关键词
D O I
10.1039/b510232b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structures of the complexes between melamine mono-cations and para-calix[4]arene sulfonic acid and calix[4]arene dihydroxyphosphonic acid have been determined. In both cases the structure is based on a bilayer motif of calixarene molecules intercalated by motifs of melamine mono-cations. While in the complex with calix[4]arene dihydroxyphosphonic acid the motifs of melamine cations are parallel to the in-layer arrangement of the calixarene, for parasulfonatocalix[4]arene there is 17.6 degrees displacement between the axes of the two motifs generating a laminate structure.
引用
收藏
页码:59 / 64
页数:6
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