Method for Accessing Nitrogen-Containing, B-Heteroaryl-Substituted 2,1-Borazaronaphthalenes

被引：28

作者：

Davies, Geraint H. M. ^{[1
]}

Zhou, Zhao-Zhao ^{[1
,2
]}

Jouffroy, Matthieu ^{[1
]}

Molander, Gary A. ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, 231 South 34th St, Philadelphia, PA 19104 USA

[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 82卷 / 01期

关键词：

CROSS-COUPLINGS;

D O I：

10.1021/acs.joc.6b02574

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The azaborine motif provides a mimic of aromatic systems through replacement of a C=C bond with a B-N bond. In particular, 2,1-borazaronaphthalenes, accessible through robust methods of synthesis and subsequent functionalization, afford an ideal platform to use for a variety of applications. However, the scope of substructures for this archetype has been limited by the lack of nitrogen-containing heteroaryls that can be incorporated within them. In this study, modified reaction conditions were developed to provide access to a wider range of substructures.

引用

页码：549 / 555

页数：7

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