Chromatographic analysis of natural and synthetic estrogens in milk and dairy products

被引:55
作者
Socas-Rodriguez, Barbara [1 ]
Asensio-Ramos, Maria [1 ]
Hernandez-Borges, Javier [1 ]
Herrera-Herrera, Antonio V. [1 ]
Angel Rodriguez-Delgado, Miguel [1 ]
机构
[1] Univ La Laguna, Fac Quim, Dept Quim Analit Nutr & Bromatol, San Cristobal la Laguna 38206, Tenerife, Spain
关键词
Chromatographic method; Dairy product; Derivatization; Estrogen; Gas chromatography; Liquid chromatography; Milk; Natural estrogen; Solid-phase extraction; Synthetic estrogen; PERFORMANCE LIQUID-CHROMATOGRAPHY; TANDEM MASS-SPECTROMETRY; STEROID-HORMONES; CARBON NANOTUBE; RISK-FACTORS; BREAST-MILK; BOVINE-MILK; COWS MILK; EXTRACTION; MICROEXTRACTION;
D O I
10.1016/j.trac.2012.10.013
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The occasional presence of relatively high amounts of natural estrogens in milk and milk derivatives and the abusive or illegal use of synthetic estrogens in dairy practices have become causes for concern, since intake of these hormones is associated with illnesses or disorders. Development of methodologies that confirm or deny the presence of natural and synthetic estrogens, their metabolites and other compounds with estrogenic activity is very important. This article provides an overview of chromatographic methods for the analysis of these compounds in milk samples and dairy products. (c) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:58 / 77
页数:20
相关论文
共 56 条
  • [1] [Anonymous], 1996, OFF J EUR COMMUN L, VL125, P21
  • [2] Liquid phase microextraction applications in food analysis
    Asensio-Ramos, Maria
    Ravelo-Perez, Lidia M.
    Angel Gonzalez-Curbelo, Miguel
    Hernandez-Borges, Javier
    [J]. JOURNAL OF CHROMATOGRAPHY A, 2011, 1218 (42) : 7415 - 7437
  • [3] Multi-walled carbon nanotubes-dispersive solid-phase extraction combined with nano-liquid chromatography for the analysis of pesticides in water samples
    Asensio-Ramos, Maria
    D'Orazio, Giovanni
    Hernandez-Borges, Javier
    Rocco, Anna
    Fanali, Salvatore
    [J]. ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2011, 400 (04) : 1113 - 1123
  • [5] Simultaneous Determination of 20 Pharmacologically Active Substances in Cow's Milk, Goat's Milk, and Human Breast Milk by Gas Chromatography-Mass Spectrometry
    Azzouz, Abdelmonaim
    Jurado-Sanchez, Beatriz
    Souhail, Badredine
    Ballesteros, Evaristo
    [J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2011, 59 (09) : 5125 - 5132
  • [6] Sex steroids, carcinogenesis, and cancer progression
    Castagnetta, L
    Granata, OM
    Cocciadiferro, L
    Saetta, A
    Polito, L
    Bronte, G
    Rizzo, S
    Campisi, I
    Agostara, B
    Carruba, G
    [J]. SIGNAL TRANSDUCTION AND COMMUNICATION IN CANCER CELLS, 2004, 1028 : 233 - 246
  • [7] Determination of non-steroidal estrogens in breast milk, plasma, urine and hair by gas chromatography/mass spectrometry
    Choi, MH
    Kim, KR
    Hong, JK
    Park, SJ
    Chung, BC
    [J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2002, 16 (24) : 2221 - 2228
  • [8] Determination of naturally occurring oestrogens and androgens in retail samples of milk and eggs
    Courant, F.
    Antignac, J. -P.
    Maume, D.
    Monteau, F.
    Andre, F.
    Le Bizec, B.
    [J]. FOOD ADDITIVES AND CONTAMINANTS PART A-CHEMISTRY ANALYSIS CONTROL EXPOSURE & RISK ASSESSMENT, 2007, 24 (12): : 1358 - 1366
  • [9] Exposure assessment of prepubertal children to steroid endocrine disruptors. 2. Determination of steroid hormones in milk, egg, and meat samples
    Courant, Frederique
    Antignac, Jean-Philippe
    Laille, Julie
    Monteau, Fabrice
    Andre, Francois
    Le Bizec, Bruno
    [J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2008, 56 (09) : 3176 - 3184
  • [10] Magnetic solid-phase extraction based on magnetic carbon nanotube for the determination of estrogens in milk
    Ding, Jun
    Gao, Qiang
    Li, Xiao-Shui
    Huang, Wei
    Shi, Zhi-Guo
    Feng, Yu-Qi
    [J]. JOURNAL OF SEPARATION SCIENCE, 2011, 34 (18) : 2498 - 2504