A hierarchically structured composite of Mn3O4/3D graphene foam for flexible nonenzymatic biosensors

被引：136

作者：

Si, Peng ^{[1
]}

Dong, Xiao-Chen ^{[1
]}

Chen, Peng ^{[1
]}

Kim, Dong-Hwan ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, Div Bioengn, Singapore 637457, Singapore

来源：

JOURNAL OF MATERIALS CHEMISTRY B | 2013年 / 1卷 / 01期

基金：

英国医学研究理事会;

关键词：

HYDROGEN-PEROXIDE; ELECTROCHEMICAL DETECTION; AMPEROMETRIC DETERMINATION; CHEMICAL SENSORS; HIGH-SENSITIVITY; GLUCOSE; ELECTRODE; NANOSHEETS; NANOTUBES;

D O I：

10.1039/c2tb00073c

中图分类号：

TB3 [工程材料学]; R318.08 [生物材料学];

学科分类号：

0805 ; 080501 ; 080502 ;

摘要：

We report a novel composite material of hierarchically structured Mn3O4 grown on three-dimensional graphene foam (3DGF). This hierarchical Mn3O4/3DGF composite was fabricated as a flexible and freestanding biosensor for nonenzymatic determination of glucose and H2O2, significant analytes in health care and food industry. The Mn3O4/3DGF-based biosensor achieved high sensitivity, large linear range and low detection limit for the detection of both analytes, due to the synergistic effects of the two materials, which combines the high electrocatalytic activity of the nanostructured Mn3O4 network, and high conductivity and large surface area of 3DGF. This enzymeless biosensor also exhibited excellent performance for real-time detection of glucose and H2O2 in serum and food samples.

引用

页码：110 / 115

页数：6

共 55 条

[1] Metal decorated graphene nanosheets as immobilization matrix for amperometric glucose biosensor [J].

Baby, Tessy Theres ;

Aravind, S. S. Jyothirmayee ;

Arockiadoss, T. ;

Rakhi, R. B. ;

Ramaprabhu, S. .

SENSORS AND ACTUATORS B-CHEMICAL, 2010, 145 (01) :71-77

[2]

Bae S, 2010, NAT NANOTECHNOL, V5, P574, DOI [10.1038/nnano.2010.132, 10.1038/NNANO.2010.132]

[3] Synthesis of Large-Area Graphene Layers on Poly-Nickel Substrate by Chemical Vapor Deposition: Wrinkle Formation [J].

Chae, Seung Jin ;

Guenes, Fethullah ;

Kim, Ki Kang ;

Kim, Eun Sung ;

Han, Gang Hee ;

Kim, Soo Min ;

Shin, Hyeon-Jin ;

Yoon, Seon-Mi ;

Choi, Jae-Young ;

Park, Min Ho ;

Yang, Cheol Woong ;

Pribat, Didier ;

Lee, Young Hee .

ADVANCED MATERIALS, 2009, 21 (22) :2328-+

[4] Nonenzymatic electrochemical glucose sensor based on MnO2/MWNTs nanocomposite [J].

Chen, Jin ;

Zhang, Wei-De ;

Ye, Jian-Shan .

ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (09) :1268-1271

[5]

Chen ZP, 2011, NAT MATER, V10, P424, DOI [10.1038/NMAT3001, 10.1038/nmat3001]

[6] Selective and sensitive electrochemical detection of glucose in neutral solution using platinum-lead alloy nanoparticle/carbon nanotube nanocomposites [J].

Cui, Hui-Fang ;

Ye, Jian-Shan ;

Zhang, Wei-De ;

Li, Chang-Ming ;

Luong, John H. T. ;

Sheu, Fwu-Shan .

ANALYTICA CHIMICA ACTA, 2007, 594 (02) :175-183

[7] Graphene-supported anatase TiO2 nanosheets for fast lithium storage [J].

Ding, Shujiang ;

Chen, Jun Song ;

Luan, Deyan ;

Boey, Freddy Yin Chiang ;

Madhavi, Srinivasan ;

Lou, Xiong Wen .

CHEMICAL COMMUNICATIONS, 2011, 47 (20) :5780-5782

[8] Electrospun Co3O4 nanofibers for sensitive and selective glucose detection [J].

Ding, Yu ;

Wang, Ying ;

Su, Liang ;

Bellagamba, Michael ;

Zhang, Heng ;

Lei, Yu .

BIOSENSORS & BIOELECTRONICS, 2010, 26 (02) :542-548

[9] 3D Graphene-Cobalt Oxide Electrode for High-Performance Supercapacitor and Enzymeless Glucose Detection [J].

Dong, Xiao-Chen ;

Xu, Hang ;

Wang, Xue-Wan ;

Huang, Yin-Xi ;

Chan-Park, Mary B. ;

Zhang, Hua ;

Wang, Lian-Hui ;

Huang, Wei ;

Chen, Peng .

ACS NANO, 2012, 6 (04) :3206-3213

[10] Electrical Detection of DNA Hybridization with Single-Base Specificity Using Transistors Based on CVD-Grown Graphene Sheets [J].

Dong, Xiaochen ;

Shi, Yumeng ;

Huang, Wei ;

Chen, Peng ;

Li, Lain-Jong .

ADVANCED MATERIALS, 2010, 22 (14) :1649-+

← 1 2 3 4 5 6 →