Sulfur-doping biomass based hard carbon as high performance anode material for sodium-ion batteries

被引:34
作者
Aristote, Nkongolo Tshamala [2 ]
Liu, Chang [1 ]
Deng, Xinglan [2 ]
Liu, Huanqing [2 ]
Gao, Jingqiang [2 ]
Deng, Wentao [2 ]
Hou, Hongshuai [2 ]
Ji, Xiaobo [2 ]
机构
[1] Hunan Inst Engn, Sch Chem & Chem Engn, Xiangtan 411104, Hunan, Peoples R China
[2] Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
基金
中国国家自然科学基金;
关键词
Initial Coulombic eff iciency; Rate performance; Sulfur; -doping; Hard carbon anode material; SIBs; REDUCED GRAPHENE OXIDE; LITHIUM-ION; ELECTROCHEMICAL PERFORMANCE; CATHODE MATERIAL; COMPOSITE; PHOSPHORUS; NANOFIBERS; NANOSHEETS; NANOTUBES; HYBRID;
D O I
10.1016/j.jelechem.2022.116769
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The intercalation/deintercalation of Na+ in the hard carbon (HC) has been widely investigated for the construction of high performances sodium-ion batteries (SIBs). In this work, a variety of sulfur-doped HCs were obtained by simple pyrolysis of the sublimated sulfur and the camphor tree (S-Cmph) derived material. When used as anode for SIBs, the S-Cmph-700 (pyrolyzed at 700celcius) delivered a capacity of 616.7 mAh/g with an ICE of 66.61 %, high than that of the untreated material pyrolyzed at 1500celcius (50.11 %) (Cmph-1500). Furthermore, excellent rate performance with specific capacities of 372.3, 323, 282.6, 252.6, 221, 181.2 mAh/g at 40, 80, 200, 400, 800 and 2000 mA g-1 can be achieved, respectively. When the current density returned at 40 mA g-1, the anode recovered a specific capacity of 356.8 mAh/g. In addition, the as-acquired anode material exhibited good cycling performance with a reversible capacity of 145.6 mAh/g over 500 cycles at 2000 mA g-1. The improved electrochemical performances of Cmph-HC anode can be attributed to the benefit of the S-doping, leading to the increase of the interlayer spacing of the anode material, which facilitates the intercalation/deintercalation of Na+ ions in the interlayer spacing of the HC material, and provided more active sites in the Cmph-HC anode for the Na+ ions storage. In addition, sulfur can reversibly react with Na+, limiting the irreversible consumption of Na+ and increase the intercalation rate of Na+ inside the anode material. This work presents a low cost, simple and effective way to synthesize a high performances anode material for the commercialization of SIBs.
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页数:7
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共 59 条
[1]   Graphene-MoS2 composite: Hydrothermal synthesis and catalytic property in hydrodesulfurization of dibenzothiophene [J].
Al-Daous, Mohammed Abdulmajeed .
CATALYSIS COMMUNICATIONS, 2015, 72 :180-184
[2]   Methods of improving the initial Coulombic efficiency and rate performance of both anode and cathode materials for sodium-ion batteries [J].
Aristote, Nkongolo Tshamala ;
Zou, Kangyu ;
Di, Andi ;
Deng, Wentao ;
Wang, Baowei ;
Deng, Xinglan ;
Hou, Hongshuai ;
Zou, Guoqiang ;
Ji, Xiaobo .
CHINESE CHEMICAL LETTERS, 2022, 33 (02) :730-742
[3]   Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications [J].
Cao, Yuliang ;
Xiao, Lifen ;
Sushko, Maria L. ;
Wang, Wei ;
Schwenzer, Birgit ;
Xiao, Jie ;
Nie, Zimin ;
Saraf, Laxmikant V. ;
Yang, Zhengguo ;
Liu, Jun .
NANO LETTERS, 2012, 12 (07) :3783-3787
[4]   1D Sub-Nanotubes with Anatase/Bronze TiO2 Nanocrystal Wall for High-Rate and Long-Life Sodium-Ion Batteries [J].
Chen, Biao ;
Meng, Yuhuan ;
Xie, Fangxi ;
He, Fang ;
He, Chunnian ;
Davey, Kenneth ;
Zhao, Naiqin ;
Qiao, Shi-Zhang .
ADVANCED MATERIALS, 2018, 30 (46)
[5]   Phenoxy Radical-Induced Formation of Dual-Layered Protection Film for High-Rate and Dendrite-Free Lithium-Metal Anodes [J].
Chen, Chao ;
Liang, Qianwen ;
Chen, Zhongxin ;
Zhu, Weiya ;
Wang, Zejun ;
Li, Yuan ;
Wu, Xianwen ;
Xiong, Xunhui .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (51) :26718-26724
[6]   KxCy phase induced expanded interlayer in ultra-thin carbon toward full potassium-ion capacitors [J].
Deng, Xinglan ;
Tian, Ye ;
Zou, Kangyu ;
Chen, Jun ;
Xiao, Xuhuan ;
Tao, Shusheng ;
Song, Zirui ;
Deng, Wentao ;
Hou, Hongshuai ;
Zou, Guoqiang ;
Ji, Xiaobo .
CARBON ENERGY, 2022, 4 (06) :1151-1168
[7]   A high-performance carbon with sulfur doped between interlayers and its sodium storage mechanism as anode material for sodium ion batteries [J].
Feng, Pingyuan ;
Wang, Wei ;
Wang, Kangli ;
Cheng, Shijie ;
Jiang, Kai .
JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 795 :223-232
[8]   Solid state lithiation-delithiation of sulphur in sub-nano confinement: a new concept for designing lithium-sulphur batteries [J].
Fu, Chengyin ;
Wong, Bryan M. ;
Bozhilov, Krassimir N. ;
Guo, Juchen .
CHEMICAL SCIENCE, 2016, 7 (02) :1224-1232
[9]   Novel electrospun SnO2@carbon nanofibers as high performance anodes for lithium-ion batteries [J].
Fu, Zhirong ;
Li, Xuefeng ;
Xu, Guirong .
CRYSTAL RESEARCH AND TECHNOLOGY, 2014, 49 (07) :441-445
[10]   Sulfur doped graphite prepared via arc discharge of carbon rods in the presence of thiophenes [J].
Glenis, S ;
Nelson, AJ ;
Labes, MM .
JOURNAL OF APPLIED PHYSICS, 1999, 86 (08) :4464-4466