Organometallic cluster complexes with face-capping arene ligands .7. Nucleophilic substitution of fluoride in a facially coordinated arene ligand

被引：8
|
作者：
Wadepohl, H
Borchert, T
Pritzkow, H
机构：
[1] Anorganisch-Chemisches Inst. der R., D-69120 Heidelberg
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 516卷 / 1-2期
关键词：
arene clusters; nucleophilic substitution; cyclopentadienyl cobalt;
D O I：
10.1016/0022-328X(96)06123-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of p-fluoro-alpha-methylstyrene with [(eta-C5H5)Co(eta-C(6)Me(6))] leads to the cluster complex [{(eta-C5H5)Co}(3)(mu(3)-eta(2):eta(2):eta(2)-p-fluoro-alpha-methylstyrene)] 1b. Nucleophilic substitution of fluoride by H- or Ph(-) takes place when Ib is treated with LiHBEt(3) or PhLi.
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页码：187 / 189
页数：3
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