Continuous dialysis of mixture of inorganic acids

被引:11
|
作者
Palaty, Zdenek [1 ]
Bendova, Helena [1 ]
机构
[1] Univ Pardubice, Inst Environm & Chem Engn, Fac Chem Technol, Studentska 573, Pardubice 53210, Czech Republic
关键词
Diffusion dialysis; Anion-exchange membrane; Sulphuric acid; Phosphoric acid; Continuous dialyzer; ANION-EXCHANGE MEMBRANES; DIFFUSION DIALYSIS; SULFURIC-ACID; RECOVERY; SEPARATION; LIQUOR; SERIES;
D O I
10.1016/j.seppur.2016.08.020
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The simultaneous transport of sulphuric and phosphoric acids through a polymeric membrane was investigated at steady state in a two-compartment counter-current dialyzer. For this purpose, an anion exchange membrane Neosepta-AFN (Astom Corporation, Tokyo, Japan) was used. This transport was quantified by four membrane mass transfer coefficients which are dependent upon the concentrations of both acids in the feed. These coefficients were determined by a two-step procedure. In the first step, the basic differential equations describing the dependences of the volumetric liquid flow rates and acid concentrations on the length coordinate in the individual compartments were numerically integrated. In the second step, an objective function was minimised to ensure the best coincidence between the experimental and calculated data. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:277 / 284
页数:8
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