Synthesis and electro-catalytic properties of a dinuclear palladium(I) 1,3-bis[(2-chloro)benzene]triazenide complex

被引：34

作者：

Chu, Jing ^{[1
]}

Xie, Xiao-hua ^{[2
]}

Yang, Shao-rong ^{[1
]}

Zhan, Shu-zhong ^{[1
]}

机构：

[1] S China Univ Technol, Coll Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China

[2] Jinan Univ, Coll Chinese Language & Culture, Guangzhou 510610, Guangdong, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2014年 / 410卷

基金：

美国国家科学基金会;

关键词：

Triazenido-palladium complex; Crystal structure; Molecular electro-catalyst; Hydrogen evolution; H-2; PRODUCTION; BINUCLEAR PALLADIUM(I); FUNCTIONAL MODELS; WATER; HYDROGENASES; ELECTROCATALYST; COBALT; COBALOXIMES; REDUCTION; LIGANDS;

D O I：

10.1016/j.ica.2013.10.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1,3-bis[(2-chloro)benzene]triazene (HL) and [Pd(CH3CN)(4)]Cl-2 gave a new dinuclear triazenido complex [Pd2L2] 1 (L = 1,3-bis[(2-chloro)benzene]triazene ion). Electrochemcial studies showed that complex 1 is capable of generating hydrogen from acetic acid in CH2Cl2. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：191 / 194

页数：4

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