Copper-catalyzed direct oxysulfonylation of alkenes with dioxygen and sulfonylhydrazides leading to β-ketosulfones

被引：284

作者：

Wei, Wei ^{[1
,2
]}

Liu, Chunli ^{[1
,2
]}

Yang, Daoshan ^{[1
,2
]}

Wen, Jiangwei ^{[1
,2
]}

You, Jinmao ^{[1
,2
,3
]}

Suo, Yourui ^{[3
]}

Wang, Hua ^{[1
,2
]}

机构：

[1] Qufu Normal Univ, Key Lab Life Organ Anal, Qufu 273165, Peoples R China

[2] Qufu Normal Univ, Key Lab Pharmaceut Intermediates & Anal Nat Med, Qufu 273165, Peoples R China

[3] Chinese Acad Sci, Northwest Inst Plateau Biol, Xining 810001, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 87期

基金：

中国国家自然科学基金;

关键词：

KETO SULFONES; MOLECULAR-OXYGEN; PEROXY RADICALS; PHOSPHONATES; DERIVATIVES; OXIDATION; SECONDARY;

D O I：

10.1039/c3cc45803b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first copper-catalyzed oxysulfonylation reaction of alkenes with dioxygen and sulfonylhydrazides for the construction of beta-ketosulfones has been developed under mild conditions without any ligand or additive.

引用

页码：10239 / 10241

页数：3

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