(2S*,4S*,5R*)-4-methyl-2-[(5S*)-3-methyl-4,5-dihydroisoxazol-5-yl]-5-phenyl-3(toluene-4-sulfonyl) oxazolidine

被引:1
|
作者
Rochon, FD [1 ]
Breau, L [1 ]
机构
[1] Univ Quebec, Dept Chim, Montreal, PQ H3C 3P8, Canada
关键词
D O I
10.1107/S0108270199005557
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, C21H24N2O4S, containing 2-isoxazoline and oxazolidine moieties, was studied in order to determine its relative configuration, which could not be determined unambiguously by NMR techniques. The results have shown that the substituents on the three C atoms of the oxazolidine cycle are all on the same side of the ring, while the aromatic group of the toluene-4-sulfonate substituent on the N atom is located on the opposite side. The 2-isoxazoline ring was found to have the 5'S* configuration.
引用
收藏
页码:1373 / 1375
页数:3
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