Potassium Dodecatungsto Cobaltate Trihydrate: A New Heterogeneous Catalyst for the Synthesis of Homoallylic Alcohols and Amines

被引：2

作者：

Nagarapu, Lingaiah ^{[1
]}

Paturi, Gopal ^{[1
]}

Apuri, Satyender ^{[1
]}

Bantu, Rajashaker ^{[1
]}

Bhavanthula, Renuka ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Chem Div 2, Hyderabad 500007, Andhra Pradesh, India

来源：

SYNTHETIC COMMUNICATIONS | 2009年 / 39卷 / 02期

关键词：

Allyltributylstannane; homoallylic alcohols; homoallylic amines; potassium dodecatungsto cobaltate trihydrate; reusability; EFFICIENT REUSABLE CATALYST; SOLVENT-FREE CONDITIONS; ONE-POT SYNTHESIS; MICROWAVE IRRADIATION; MILD; K5COW12O40-CENTER-DOT-3H(2)O;

D O I：

10.1080/00397910802374109

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and efficient procedure has been developed for one-pot synthesis of homoallylic alcohols and amines in good to excellent yields using a variety of aldehydes, amines, and allyltributylstannane in the presence of a catalytic amount of potassium dodecatungsto cobaltate trihydrate (K5CoW12O403H2O) as a heterogeneous catalyst at room temperature. The catalyst exhibited remarkable reusability.

引用

页码：355 / 365

页数：11

共 50 条

[41] Development of heterogeneous catalyst systems for the continuous synthesis of chiral amines via asymmetric hydrogenation
Yasukawa, Tomohiro
Masuda, Ryusuke
Kobayashi, Shu
NATURE CATALYSIS, 2019, 2 (12) : 1088 - 1092
[42] Synthesis of homoallylic (but-3-enylic) alcohols from aldehydes with allylic chlorides, tin(II) chloride and potassium iodide in water
Houllemare, D
Outurquin, F
Paulmier, C
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (11): : 1629 - 1632
[43] Development of heterogeneous catalyst systems for the continuous synthesis of chiral amines via asymmetric hydrogenation
Tomohiro Yasukawa
Ryusuke Masuda
Shū Kobayashi
Nature Catalysis, 2019, 2 : 1088 - 1092
[44] Sulphamic acid: An efficient, cost-effective and recyclable solid acid catalyst for three-component synthesis of homoallylic amines
Yadav, J. S.
Ather, Hissana
Rao, P. Purushothama
Rao, R. Srinivasa
Nagaiah, K.
Prasad, A. R.
CATALYSIS COMMUNICATIONS, 2006, 7 (10) : 797 - 801
[45] Magnesium-Cadmium Chloride, a Bimetallic Catalyst System for the Allylation of Aldehydes with Allyl Bromide: An Efficient Protocol for the Synthesis of Homoallylic Alcohols
Narsaiah, A. Venkat
Reddy, A. Ramesh
Rao, Y. Gopala
Kumar, E. Vijay
Prakasham, R. S.
Reddy, V. Subba
Yadava, Jhillu S.
SYNTHESIS-STUTTGART, 2008, (21): : 3461 - 3464
[46] Melamine trisulfonic acid: A new, efficient and reusable catalyst for the protection of alcohols, phenols, aldehydes and amines
Shirini, Farhad
Zolfigol, Mohammad A.
Albadi, Jalal
Rastegar, Toktam F.
IRANIAN JOURNAL OF CATALYSIS, 2011, 1 (01): : 11 - 17
[47] Sol–gel derived LaFeO3/SiO2 nanocomposite: synthesis, characterization and its application as a new, green and recoverable heterogeneous catalyst for the efficient acetylation of amines, alcohols and phenols
Saeed Farhadi
Kosar Jahanara
Asma Sepahdar
Journal of the Iranian Chemical Society, 2014, 11 : 1103 - 1112
[48] Polyaniline nanofiber supported FeCl3: An efficient and reusable heterogeneous catalyst for the acylation of alcohols and amines with acetic acid
Likhar, Pravin R.
Arundhathi, R.
Ghosh, Sutapa
Kantam, M. Lakshmi
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 302 (1-2) : 142 - 149
[49] Convenient Synthesis of Benziodazolone: New Reagents for Direct Esterification of Alcohols and Amidation of Amines
Shea, Michael T.
Rohde, Gregory T.
Vlasenko, Yulia A.
Postnikov, Pavel S.
Yusubov, Mekhman S.
Zhdankin, Viktor V.
Saito, Akio
Yoshimura, Akira
MOLECULES, 2021, 26 (23):
[50] A NEW CHIRAL CATALYST FOR THE ENANTIOSELECTIVE SYNTHESIS OF SECONDARY ALCOHOLS AND DEUTERATED PRIMARY ALCOHOLS BY CARBONYL REDUCTION
COREY, EJ
LINK, JO
TETRAHEDRON LETTERS, 1989, 30 (46) : 6275 - 6278

← 1 2 3 4 5 →