Potassium Dodecatungsto Cobaltate Trihydrate: A New Heterogeneous Catalyst for the Synthesis of Homoallylic Alcohols and Amines

被引：2

作者：

Nagarapu, Lingaiah ^{[1
]}

Paturi, Gopal ^{[1
]}

Apuri, Satyender ^{[1
]}

Bantu, Rajashaker ^{[1
]}

Bhavanthula, Renuka ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Chem Div 2, Hyderabad 500007, Andhra Pradesh, India

来源：

SYNTHETIC COMMUNICATIONS | 2009年 / 39卷 / 02期

关键词：

Allyltributylstannane; homoallylic alcohols; homoallylic amines; potassium dodecatungsto cobaltate trihydrate; reusability; EFFICIENT REUSABLE CATALYST; SOLVENT-FREE CONDITIONS; ONE-POT SYNTHESIS; MICROWAVE IRRADIATION; MILD; K5COW12O40-CENTER-DOT-3H(2)O;

D O I：

10.1080/00397910802374109

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and efficient procedure has been developed for one-pot synthesis of homoallylic alcohols and amines in good to excellent yields using a variety of aldehydes, amines, and allyltributylstannane in the presence of a catalytic amount of potassium dodecatungsto cobaltate trihydrate (K5CoW12O403H2O) as a heterogeneous catalyst at room temperature. The catalyst exhibited remarkable reusability.

引用

页码：355 / 365

页数：11

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