共 41 条
Nucleic acid-mediated gold oxidation: novel biolithography for surface microfabrication and new insight into gold-based biomaterials
被引:16
作者:
Yang, Peng
[1
,2
]
Zhang, Xu
[3
]
机构:
[1] Shaanxi Normal Univ, Sch Chem & Chem Engn, Xian 710062, Peoples R China
[2] Duke Univ, Dept Biomed Engn, Durham, NC 27705 USA
[3] Tianjin Med Univ, Hosp Stomatol, Sch Dent, Tianjin 300070, Peoples R China
关键词:
SELF-ASSEMBLED MONOLAYERS;
DIRECTED OXIDATION;
DNA;
NANOPARTICLES;
COMPLEXES;
GOLD(III);
NANORODS;
IONS;
CRYSTALLIZATION;
AGGREGATION;
D O I:
10.1039/c2cc33614f
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
In Nature, certain organisms can perform microbial corrosion on base metals by oxidation of neutral metallic atoms (H. L. Ehrlich, Appl. Microbiol. Biotechnol., 1997). Herein we describe the first discovery of biological nucleic acids able to catalyze and mediate gold oxidation from neutral Au-0 to trivalent Au(III) under certain oxidative environments provided by mild oxidizing reagent N-bromosuccinimide or amino acids. A new biolithography technique for gold patterning is further developed.
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页码:8787 / 8789
页数:3
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