One-pot synthesis of nitrogen and sulfur co-doped graphene supported MoS2 as high performance anode materials for lithium-ion batteries

被引:47
作者
Liu, Qiuhong [1 ,2 ]
Wu, Zhenjun [2 ]
Ma, Zhaoling [1 ]
Dou, Shuo [1 ]
Wu, Jianghong [1 ]
Tao, Li [1 ]
Wang, Xin [1 ]
Ouyang, Canbing [1 ]
Shen, Anli [1 ]
Wang, Shuangyin [1 ]
机构
[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chem Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
[2] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
graphene; MoS2; lithium-ion batteries; anode; durability; EVOLUTION;
D O I
10.1016/j.electacta.2015.01.193
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Nitrogen and sulfur co-doped graphene supported MoS2 (MoS2/NS-G) nanosheets were prepared through a one-pot thermal annealing method. The as prepared samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Raman spectra and electrochemical techniques. The MoS2/NS-G shows high reversible capacity about 1200 mAh/g at current density of 150 mA/g and excellent stability in Li-ion batteries. It was demonstrated the co-doping of graphene by N and S could significantly enhance the durability of MoS2 as anode materials for Li-ion batteries. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:298 / 303
页数:6
相关论文
共 25 条
[1]   Nonvolatile Memory Cells Based on MoS2/Graphene Heterostructures [J].
Bertolazzi, Simone ;
Krasnozhon, Daria ;
Kis, Andras .
ACS NANO, 2013, 7 (04) :3246-3252
[2]   L-Cysteine-Assisted Synthesis of Layered MoS2/Graphene Composites with Excellent Electrochemical Performances for Lithium Ion Batteries [J].
Chang, Kun ;
Chen, Weixiang .
ACS NANO, 2011, 5 (06) :4720-4728
[3]   In situ synthesis of MoS2/graphene nanosheet composites with extraordinarily high electrochemical performance for lithium ion batteries [J].
Chang, Kun ;
Chen, Weixiang .
CHEMICAL COMMUNICATIONS, 2011, 47 (14) :4252-4254
[4]   Electron-hole transport and photovoltaic effect in gated MoS2 Schottky junctions [J].
Fontana, Marcio ;
Deppe, Tristan ;
Boyd, Anthony K. ;
Rinzan, Mohamed ;
Liu, Amy Y. ;
Paranjape, Makarand ;
Barbara, Paola .
SCIENTIFIC REPORTS, 2013, 3
[5]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[6]   MoS2 Nanoplates Consisting of Disordered Graphene-like Layers for High Rate Lithium Battery Anode Materials [J].
Hwang, Haesuk ;
Kim, Hyejung ;
Cho, Jaephil .
NANO LETTERS, 2011, 11 (11) :4826-4830
[7]   Identification of active edge sites for electrochemical H2 evolution from MoS2 nanocatalysts [J].
Jaramillo, Thomas F. ;
Jorgensen, Kristina P. ;
Bonde, Jacob ;
Nielsen, Jane H. ;
Horch, Sebastian ;
Chorkendorff, Ib .
SCIENCE, 2007, 317 (5834) :100-102
[8]   Magnesium and magnesium-silicide coated silicon nanowire composite anodes for lithium-ion batteries [J].
Kohandehghan, Alireza ;
Kalisvaart, Peter ;
Kupsta, Martin ;
Zahiri, Beniamin ;
Amirkhiz, Babak Shalchi ;
Li, Zhipeng ;
Memarzadeh, Elmira L. ;
Bendersky, Leonid A. ;
Mitlin, David .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (05) :1600-1612
[9]   Charge Transfer in the MoS2/Carbon Nanotube Composite [J].
Koroteev, V. O. ;
Bulusheva, L. G. ;
Asanov, I. P. ;
Shlyakhova, E. V. ;
Vyalikh, D. V. ;
Okotrub, A. V. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (43) :21199-21204
[10]   Molybdenum disulfide nanowires and nanoribbons by electrochemical/chemical synthesis [J].
Li, Q ;
Walter, EC ;
van der Veer, WE ;
Murray, BJ ;
Newberg, JT ;
Bohannan, EW ;
Switzer, JA ;
Hemminger, JC ;
Penner, RM .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (08) :3169-3182