Coordination design of artificial metalloproteins utilizing protein vacant space

被引:95
作者
Ueno, Takafumi [2 ,3 ]
Abe, Satoshi [2 ]
Yokoi, Norihiko [2 ]
Watanabe, Yoshihito [1 ]
机构
[1] Nagoya Univ, Res Ctr Mat Sci, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Nagoya, Aichi 4648602, Japan
[3] Japan Sci & Technol Agcy, PRESTO, Tokyo, Japan
基金
日本科学技术振兴机构;
关键词
myoglobin; ferritin; nanoparticle; biomineralization; metalloenzyme; heme;
D O I
10.1016/j.ccr.2007.04.007
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Design of artificial metalloproteins is one of the most important subjects in the field of bioinorganic chemistry. In order to prepare them, vacant space of proteins has been utilized because it gives us unique chemical environment to construct catalysts and materials. This article reviews on preparation methods and properties of metal/protein composites. The discussion includes our recent results and development in the screening of composites, crystal structures, molecular design of bio-inspired systems concerning catalysts, electrochemistry, and materials. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:2717 / 2731
页数:15
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