Electrochemical Reduction of Nitrous Oxide (N2O) catalysed by Tetraaminophthalocyanatocobalt(II) Adsorbed on a Graphite Electrode in Aqueous Solution

被引：0

作者：

Zhang, Jiujun ^{[1
]}

Tse, Yu-Hong ^{[1
]}

Lever, A. B. P. ^{[1
]}

Pietro, W. J. ^{[1
]}

机构：

[1] York Univ, Dept Chem, Toronto, ON M3J 1P3, Canada

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 1997年 / 1卷 / 04期

基金：

加拿大自然科学与工程研究理事会;

关键词：

phthalocyanine; cobalt; nitrous oxide; electrocatalysis;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The surface electrochemical response of the Co-II/Co-I redox process of tetraaminophthalocyaninatocobalt(II) (Co(II)TAPc) adsorbed on a graphite electrode, was studied in the pH range of 2-13. In aqueous solution, the Co(II)TAPc adsorbed graphite electrode displays very strong electrocatalytic activity toward N2O reduction to N-2, a process which was examined by cyclic and rotating disk electrode voltammetries. The possible application of this Co(II)TAPc modified electrode in N2O analysis was explored. (C) 1997 by John Wiley & Sons, Ltd.

引用

页码：323 / 331

页数：9

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