Nonequilibrium differential capacitance corresponding to the generalized model of the surface layer and its regression analysis

被引：1

作者：

Damaskin, B. B. ^{[1
]}

Safonov, V. A. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119992, Russia

来源：

RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2009年 / 45卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

generalized model of surface layer (GMSL); differential capacitance; regression analysis; adsorption of n-C4H9OH; ADSORPTION; MOLECULES;

D O I：

10.1134/S1023193509010169

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Equations that describe the nonequilibrium differential capacitance C of an electrode subjected to adsorption of organic molecules under the conditions where this adsorption strictly follows the generalized model of the surface layer (GMSL) are derived. Using the developed programs, the dependences of C (omega) on the electrode potential phi at different concentrations of an organic substance are calculated. A regression analysis procedure is developed that allows one to obtain a set of GMSL parameters describing the dense layer capacitance in NaF solutions with different contents of n-C4H9OH.

引用

页码：116 / 122

页数：7

共 10 条

[1] Nonequilibrium differential capacitance corresponding to the generalized model of the surface layer and its regression analysis
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