Immobilization of rhenium compounds in ionic liquids

被引：0
|
作者：
Leszczynska-Sejda, Katarzyna [1 ]
Benke, Grzegorz [1 ]
Anyszkiewicz, Krystyna [1 ]
Chmielarz, Andrzej [1 ]
机构：
[1] Inst Met Niezelaznych, PL-44100 Gliwice, Poland
来源：
PRZEMYSL CHEMICZNY | 2008年 / 87卷 / 10期
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D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
MeReO3 was synthesized by conversion of AgReO4, and used as catalyst for epoxidation of cyclohexene and 1,5-cyclooctadiene with urea-H2O2 complex in 5 com. ionic liqs. The products were sepd. from the reaction mixt. by extn. with org. solvents (Et2O, pentane, cyclopentane). The products contained also resp. diols formed by spontaneous opening the oxirane rings. 1-Butyl-3-methytimldazolium tetrafluoroborate was the most efficient medium of the reactions studied. The phosphonium salts used showed lower applicability as reaction mediums.
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页码：1035 / 1038
页数：4
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