NH2-MIL-53(Al) and NH2-MIL-101(Al) in sulfur-containing copolyimide mixed matrix membranes for gas separation

被引：171
作者：
Seoane, Beatriz [1 ,2 ]
Tellez, Carlos [1 ,2 ]
Coronas, Joaquin [1 ,2 ]
Staudt, Claudia [3 ]
机构：
[1] Univ Zaragoza, Dept Chem & Environm Engn, Zaragoza 50018, Spain
[2] Univ Zaragoza, INA, Zaragoza 50018, Spain
[3] BASF SE, GMM M B001, D-67056 Ludwigshafen, Germany
来源：
SEPARATION AND PURIFICATION TECHNOLOGY | 2013年 / 111卷
关键词：
Metal-organic framework; NH2-MIL-53(Al); NH2-MIL-101(Al); Mixed-matrix membrane; Gas separation; METAL-ORGANIC FRAMEWORK; INORGANIC FILLERS; MIL-53; MOFS; PERMEABILITY; PERFORMANCE; CO2/CH4; PERVAPORATION; CO2;
D O I：
10.1016/j.seppur.2013.03.034
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Amino functionalized MOFs (NH2-MIL-53(Al) or NH2-MIL-101(Al)) were used as dispersed phase in the fabrication of mixed matrix membranes (MMMs) with a polymer matrix of sulfur-containing copolyimides (6FDA:DSDA/4MPD:4,4'-SDA 1:1 (polymer P1) or 6FDA/4MPD:4,4'-SDA 1:1 (polymer P2)). The gas separation properties of the MMMs obtained were tested for permeation of H-2, CH4 and CO2. Membranes comprising polymer P1 showed better interaction with the fillers used than those with polymer P2, and therefore better separation properties, especially for NH2-MIL-101(Al). Upon NH2-MIL-101(Al) loading the performance of pure polymer was improved approaching the Robeson 1991 H-2/CH4 and CO2/CH4 upper bound limits with high permeabilities, e.g. 114, 71 and 1.7 Barrer for H-2, CO2 and CH4, respectively, using 10 wt.% NH2-MIL-101(Al)@P1. These improvements are related to the pore size of the filler, the flexibility and functional groups of sulfone-containing DSDA, and polymer rigidification. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：72 / 81
页数：10
相关论文
共 47 条
[1]   Metal organic framework mixed matrix membranes for gas separations [J].
Adams, Ryan ;
Carson, Cantwell ;
Ward, Jason ;
Tannenbaum, Rina ;
Koros, William .
MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 131 (1-3) :13-20
[2]   Synthesis and Modification of a Functionalized 3D Open-Framework Structure with MIL-53 Topology [J].
Ahnfeldt, Tim ;
Gunzelmann, Daniel ;
Loiseau, Thierry ;
Hirsemann, Dunja ;
Senker, Juergen ;
Ferey, Gerard ;
Stock, Norbert .
INORGANIC CHEMISTRY, 2009, 48 (07) :3057-3064
[3]   Amine functionalised metal organic frameworks (MOFs) as adsorbents for carbon dioxide [J].
Arstad, Bjornar ;
Fjellvag, Helmer ;
Kongshaug, Kjell Ove ;
Swang, Ole ;
Blom, Richard .
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2008, 14 (06) :755-762
[4]   A High-Performance Gas-Separation Membrane Containing Submicrometer-Sized Metal-Organic Framework Crystals [J].
Bae, Tae-Hyun ;
Lee, Jong Suk ;
Qiu, Wulin ;
Koros, William J. ;
Jones, Christopher W. ;
Nair, Sankar .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (51) :9863-9866
[5]   MOF-containing mixed-matrix membranes for CO2/CH4 and CO2/N2 binary gas mixture separations [J].
Basu, Subhankar ;
Cano-Odena, Angels ;
Vankelecom, Ivo F. J. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2011, 81 (01) :31-40
[6]   Hybrid membrane materials with different metal-organic frameworks (MOFs) for gas separation [J].
Car, Anja ;
Stropnik, Chrtomir ;
Peinemann, Klaus-Viktor .
DESALINATION, 2006, 200 (1-3) :424-426
[7]   Amine-Functionalized MIL-53 Metal-Organic Framework in Polyimide Mixed Matrix Membranes for CO2/CH4 Separation [J].
Chen, Xiao Yuan ;
Vinh-Thang, Hoang ;
Rodrigue, Denis ;
Kaliaguine, Serge .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (19) :6895-6906
[8]   Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation [J].
Chung, Tai-Shung ;
Jiang, Lan Ying ;
Li, Yi ;
Kulprathipanja, Santi .
PROGRESS IN POLYMER SCIENCE, 2007, 32 (04) :483-507
[9]   Adsorption and Separation of Light Gases on an Amino-Functionalized Metal-Organic Framework: An Adsorption and In Situ XRD Study [J].
Couck, Sarah ;
Gobechiya, Elena ;
Kirschhock, Christine E. A. ;
Serra-Crespo, Pablo ;
Juan-Alcaniz, Jana ;
Joaristi, Alberto Martinez ;
Stavitski, Eli ;
Gascon, Jorge ;
Kapteijn, Freek ;
Baron, Gino V. ;
Denayer, Joeri F. M. .
CHEMSUSCHEM, 2012, 5 (04) :740-750
[10]   An Amine-Functionalized MIL-53 Metal-Organic Framework with Large Separation Power for CO2 and CH4 [J].
Couck, Sarah ;
Denayer, Joeri F. M. ;
Baron, Gino V. ;
Remy, Tom ;
Gascon, Jorge ;
Kapteijn, Freek .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (18) :6326-+
12345