Monomeric magnesium 1-azaallyl and β-diketiminato complexes derived from the bis(trimethylsilyl)methyl ligand:: The X-ray structure of the four-coordinate planar magnesium complex [Mg{N(R)C(But)C(H)R}2] and of [Mg({N(R)C(Ph)}2CH)2]

被引：56

作者：

Caro, CF ^{[1
]}

Hitchcock, PB ^{[1
]}

Lappert, MF ^{[1
]}

机构：

[1] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 15期

关键词：

D O I：

10.1039/a904196f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [K{N(R)C(Bu-t)C(H)R}](n) {[K(LL')](n)} or [Li({N(R)C(Ph)}(2)CH)](2) {= [Li(LL)](2)} with magnesium bromide yielded the monomeric, crystalline magnesium complexes [Mg(LL')(2)] 1 or [Mg(LL)(2)] 2, which have been structurally characterised; 1 has the magnesium atom in an unusual planar environment.

引用

页码：1433 / 1434

页数：2

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