Lanthanide acylpyrazolonates: synthesis, properties and structural features

被引：27

作者：

Belousov, Yu A. ^{[1
]}

Drozdov, A. A. ^{[2
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Mat Sci, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL REVIEWS | 2012年 / 81卷 / 12期

关键词：

HETEROCYCLIC BETA-DIKETONES; METAL-COMPLEXES; CRYSTAL-STRUCTURE; ELECTROLUMINESCENCE PROPERTIES; 2ND-HARMONIC GENERATION; CERIUM COMPLEXES; TERBIUM; PHOTOLUMINESCENCE; COORDINATION; LIGANDS;

D O I：

10.1070/RC2012v081n12ABEH004255

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Data concerning synthesis and structural features of lanthanide acylpyrazolonates including tris-complexes, heteroligand complexes with aromatic N-heterocycles and phosphorus-containing ligands and anionic tetrakis-complexes are summarized. The effect of substituents in the acyl moiety on the structural and luminescence properties of the compounds is considered. The key features of acylpyrazolonate coordination polymers and bis(acylpyrazolonates) of rare earth elements are discussed. The bibliography includes 71 references.

引用

页码：1159 / 1169

页数：11

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