Palm vein recognition is a new biometric identification technology, mainly used for authentication. This paper for the first time applies it to supervise and manage clients, couriers, the warehouse administrators in the valuables logistics. Aiming at when valuables are lost, damaged, it guarantees responsibilities to individuals. we use contactless palm vein recognition technology based on the block and partial least squares, and do experiments on CASIA gallery. The experimental results shows when the block size is 4x4 and principal component number is 240, the recognition performance is best, then the correct recognition rate is 99.34%, the deterrent rate is 0.66%, the false reject rate is 0.60%, the recognition time is 0.0379s. Obviously, this algorithm has practical value and meets the application requirements of the valuables logistics.