Tetraaryltetraanthra[2,3]porphyrins: Synthesis, Structure, and Optical Properties

被引：43

作者：

Filatov, Mikhail A. ^{[1
]}

Baluschev, Stanislav ^{[1
,2
]}

Ilieva, Iliyana Z. ^{[2
]}

Enkelmann, Volker ^{[1
]}

Miteva, Tzenka ^{[3
]}

Landfester, Katharina ^{[1
]}

Aeshchenkov, Sergey E. ^{[4
]}

Cheprakov, Andrei V. ^{[4
]}

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

[2] Sofia Univ St Kliment Ochridski, Fac Phys, Opt & Spect Dept, Sofia 1164, Bulgaria

[3] Sony Deutschland GmbH, Mat Sci Lab, D-70327 Stuttgart, Germany

[4] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 24期

关键词：

PHOTOPHYSICAL PROPERTIES; ELECTRONIC-STRUCTURES; CONJUGATION PATHWAYS; FUSED PORPHYRINS; UP-CONVERSION; NONPLANAR; TETRABENZOPORPHYRIN; ABSORPTION; EFFICIENT; SPECTRA;

D O I：

10.1021/jo302135q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A synthetic route to symmetrical tetraaryltetraanthra[2,3]porphyrins (Ar(4)TAPs) was developed. Ar(4)TAPs bearing various substituents in meso-phenyls and anthracene residues were prepared from the corresponding pyrrolic precursors. The synthesized porphyrins possess high solubility and exhibit remarkably strong absorption bands in the near-infrared region (790-950 nm). The scope of the method, selection of the peripheral substituents, choice of the metal, and their influence on the optical properties are discussed together with the first X-ray crystallographic data for anthraporphyrin.

引用

页码：11119 / 11131

页数：13

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