Polyoxopalladate-Loaded Metal-Organic Framework (POP@MOF): Synthesis and Heterogeneous Catalysis

被引：32

作者：

Bhattacharya, Saurav ^{[1
]}

Ayass, Wassim W. ^{[1
]}

Taffa, Dereje H. ^{[2
]}

Nisar, Talha ^{[3
]}

Balster, Torsten ^{[3
]}

Hartwig, Andreas ^{[4
,5
]}

Wagner, Veit ^{[3
]}

Wark, Michael ^{[2
]}

Kortz, Ulrich ^{[1
]}

机构：

[1] Jacobs Univ, Dept Life Sciemes Aid Chem, D-28759 Bremen, Germany

[2] Carl von Ossietzky Univ Oldenburg, Inst Chem, D-26129 Oldenburg, Germany

[3] Jacobs Univ, Dept Phys & Earth Sci, D-28759 Bremen, Germany

[4] Fraunhofer Inst Mfg Technol & Adv Mat IFAM, D-28359 Bremen, Germany

[5] Univ Bremen, Dept Biol Chem 2, D-28359 Bremen, Germany

来源：

INORGANIC CHEMISTRY | 2020年 / 59卷 / 15期

关键词：

CROSS-COUPLING REACTION; SUZUKI-MIYAURA; RIBOSOMAL-SUBUNIT; POLYOXOMETALATE; PALLADIUM; CLUSTERS; PD; IMMOBILIZATION; MIL-101(CR); EFFICIENT;

D O I：

10.1021/acs.inorgchem.0c00875

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report on the synthesis and characterization of the first polyoxo-noble-metalate-containing metal-organic framework (MOF) material, wherein the preformed MIL-101 has been impregnated with the discrete, cuboid-shaped polyoxopalladate [Pd13Se8O32](6-) (Pd13Se8), leading to the composite Pd13Se8@MIL-101. This material was characterized by FTIR, TGA, elemental analysis, powder-XRD, N-2 sorption (BET), SEM-EDX, and XPS. Furthermore, the Pd13Se8@MIL-101 composite was shown to be an effective, stable, and recyclable heterogeneous precatalyst for the Suzuki-Miyaura cross-coupling reaction at room temperature utilizing environmentally benign solvents, such as water and methanol.

引用

页码：10512 / 10521

页数：10

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