Spontaneous formation of a chiral supramolecular superhelix in the crystalline state using a single-stranded tetranuclear metallohelicate

被引：68
作者：
Akine, Shigehisa [1 ]
Matsumoto, Takashi [1 ]
Nabeshima, Tatsuya [1 ]
机构：
[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 38期
关键词：
D O I：
10.1039/b810426c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An unprecedented one-handed coiled-coil structure was formed in the crystal of a Zn(3)La tetranuclear metallohelicate, in which the handedness of both the helical component and the helical array was well controlled by the chiral auxiliary of the flexible acyclic ligand.
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收藏
页码：4604 / 4606
页数：3
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