The C-S-H gel of Portland cement mortars: Part I. The interpretation of energy-dispersive X-ray microanalyses from scanning electron microscopy, with some observations on C-S-H, AFm and AFt phase compositions

Scanning electron microscopy (SEM) microanalyses of the calcium-silicate-hydrate (C-S-H) gel in Portland cement pastes rarely represent single phases. Essential experimental requirements are summarised and new procedures for interpreting the data are described. These include, notably, plots of Si/Ca against other atom ratios, 3D plots to allow three such ratios to be correlated and solution of linear simultaneous equations to test and quantify hypotheses regarding the phases contributing to individual microanalyses. Application of these methods to the C-S-H gel of a Way-old mortar identified a phase with Al/Ca = 0.67 and S/Ca = 0.33, which we consider to be a highly substituted ettringite of probable composition C(6)A(2)(S) over bar H-2(34) or {Ca-6[Al(OH)(6)](2).24H(2)O}(SO4)(2)[Al(OH)(4)](2). If this is true for Portland cements in general, it might explain observed discrepancies between observed and calculated aluminate concentrations in the pore solution. The C-S-H gel of a similar mortar aged 600 days contained unsubstituted ettringite and an AFm phase with S/Ca = 0.125. (C) 2003 Elsevier Science Ltd. All rights reserved.