Enhanced Hydrolysis of p-Nitrophenyl Picolinate by Schiff Base Mn(III) Complexes in Gemini 16-6-16 Micelles

被引：10

作者：

Xu, Bin ^{[1
]}

Jiang, Weidong ^{[1
]}

Li, Jianzhang ^{[1
]}

Lin, Qi ^{[2
]}

Liu, Fuan ^{[1
]}

机构：

[1] Sichuan Univ Sci & Engn, Dept Chem, Key Lab Green Chem & Technol, Sichuan Zigong 643000, Peoples R China

[2] Minjiang Univ, Dept Chem & Chem Engn, Fujian Fuzhou, Peoples R China

来源：

JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY | 2008年 / 29卷 / 09期

关键词：

Gemini surfactant; hydrolysis; PNPP; Schiff base Mn(III) complexes; structural differences;

D O I：

10.1080/01932690701866781

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrolysis of p-nitrophenyl picolinate (PNPP) catalyzed by three Schiff base Mn(III) complexes (MnL2Cl) were investigated in Gemini 16-6-16 micelle media. MnL21 Cl/16 - 6 - 16, MnL22 Cl/16 - 6 - 16 and MnL23 Cl/16 - 6 - 16 systems give 835-, 969-, and 1931-fold rate enhancements in the hydrolysis of PNPP under the comparable conditions, respectively. Moreover, Effects of varied micelles on the reactivity of PNPP hydrolysis were especially studied. The results obtained indicate that rates of hydrolysis of PNPP are approximately 1.5- and 4-fold larger in Gemini 16-6-16 micelles than in CTAB micelles and Brij35 micelles, respectively. Effects of ligand structure on the activities of these three complexes are discussed in detail.

引用

页码：1319 / 1324

页数：6

共 23 条

[1] Hydrolytic cleavage of bis(p-nitrophenyl) phosphate by Schiff base MnIII complexes containing morpholine pendants in Gemini 16-6-16 micelles
Weidong Jiang
Bin Xu
Junbo Zhong
Jianzhang Li
Fuan Liu
Journal of Chemical Sciences, 2008, 120 : 411 - 417
[2] Hydrolytic cleavage of bis(p-nitrophenyl) phosphate by Schiff base MnIII complexes containing morpholine pendants in Gemini 16-6-16 micelles
Jiang, Weidong
Xu, Bin
Zhong, Junbo
Li, Jianzhang
Liu, Fuan
JOURNAL OF CHEMICAL SCIENCES, 2008, 120 (04) : 411 - 417
[3] Gemini metallomicellar catalysis:: Hydrolysis of p-nitrophenyl picolinate catalyzed by Cu(II) and Ni(II) complexes of macrocyclic ligands in gemini surfactant micelles
Qiu, Ling-Guang
Jiang, Xia
Gu, Li-Na
Hu, Gang
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 277 (1-2) : 15 - 20
[4] Hydrolysis kinetics of p-nitrophenylpicolinate catalyzed by schiff base Mn(III) complexes in Gemini 16-2-16 micellar solutiony
Xu, Bin
Jiang, Weidong
Zhang, Jin
Fan, Guangyin
Li, Jianzhang
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY, 2009, 7 (03): : 542 - 549
[5] Effects of Various Schiff Base Ligands and Micelles on the Hydrolytic Kinetics of p-Nitrophenyl Picolinate
Xu, Bin
Jiang, Weidong
Zhong, Junbo
Zhang, Jin
Huang, Shengtian
Li, Jianzhang
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2010, 31 (07) : 962 - 967
[6] Metallomicellar catalysis:: Hydrolysis of p-nitrophenyl picolinate catalyzed by Cu(II) complexes of triazole-based ligands in cationic gemini surfactant micelles
Qiu, LG
Xie, AJ
Shen, YH
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 244 (1-2) : 58 - 63
[7] Hydrolysis of p-Nitrophenyl Picolinate Catalyzed by Mono-Schiff Base Complexes with Aza-crown Ether or Morpholino Pendants
Li Jianzhang
Jiang Weidong
Feng Famei
Xu Bin
Hu Wei
Zhang Jin
Qin Shengying
CHINESE JOURNAL OF CHEMISTRY, 2009, 27 (02) : 372 - 378
[8] Hydrolytic reactivities of p-nitrophenyl picolinate accelerated by Schiff base Co(II) complexes in micellar solutions
Xu, Bin
Jiang, Weidong
Li, Jianzhang
Zhong, Junbo
COLLOID AND POLYMER SCIENCE, 2010, 288 (03) : 347 - 352
[9] Hydrolytic reactivities of p-nitrophenyl picolinate accelerated by Schiff base Co(II) complexes in micellar solutions
Bin Xu
Weidong Jiang
Jianzhang Li
Junbo Zhong
Colloid and Polymer Science, 2010, 288 : 347 - 352
[10] Metal-promoted hydrolysis of bis(p-nitrophenyl)phosphate by trivalent manganese complexes with Schiff base ligands in Gemini micellar solution
Jiang, Weidong
Xu, Bin
Lin, Qi
Li, Jianzhang
Liu, Fuan
Zeng, Xiancheng
Chen, Hua
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 315 (1-3) : 103 - 109

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