Dual role of alkynyl halides in one-step synthesis of alkynyl epoxides

被引：59

作者：

Trofimov, Alexander ^{[1
]}

Chernyak, Natalia ^{[1
]}

Gevorgyan, Vladimir ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Chicago, IL 60607 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 41期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ja806178r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It was demonstrated that alkynyl halides could serve as a source of Br+ and acetylide ions in the same transformation. This allowed for the efficient one-step preparation of alkynyl epoxides, important organic building blocks, from readily available starting materials.

引用

页码：13538 / +

页数：3

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