A reversible and stable flake-like LiCoO2 cathode for lithium ion batteries

被引:45
作者
Wei, Tao [1 ,2 ]
Zeng, Rui [2 ]
Sun, Yongming [2 ]
Huang, Yunhui [2 ]
Huang, Kevin [1 ]
机构
[1] Univ S Carolina, Dept Mech Engn, Columbia, SC 29208 USA
[2] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mold Technol, Wuhan 430074, Peoples R China
基金
中国国家自然科学基金;
关键词
HIGH-RATE PERFORMANCE; NANOSTRUCTURED MATERIALS; INTERCALATION CATHODE; ENERGY-CONVERSION; COO;
D O I
10.1039/c3cc48559e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A dense and thick flake-like cathode structure was demonstrated to have a preferential crystallographic orientation for Li+ migration and a better tolerance to cracking, both of which enable a reversible and stable capacity at moderate rates from 0.1 to 2 C.
引用
收藏
页码:1962 / 1964
页数:3
相关论文
共 29 条
[11]   Nanostructured materials for electrochemical energy conversion and storage devices [J].
Guo, Yu-Guo ;
Hu, Jin-Song ;
Wan, Li-Jun .
ADVANCED MATERIALS, 2008, 20 (15) :2878-2887
[12]   LiAlyCo1-yO2 (R(3)over-bar-m) intercalation cathode for rechargeable lithium batteries [J].
Jang, YI ;
Huang, BY ;
Wang, HF ;
Sadoway, DR ;
Ceder, G ;
Chiang, YM ;
Liu, H ;
Tamura, H .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (03) :862-868
[13]   Effect of LiCoO2 Cathode Nanoparticle Size on High Rate Performance for Li-Ion Batteries [J].
Jo, Minki ;
Hong, Young-Sik ;
Choo, Jaebum ;
Cho, Jaephil .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (06) :A430-A434
[14]   Enhanced Power and Rechargeability of a LiO2 Battery Based on a Hierarchical-Fibril CNT Electrode [J].
Lim, Hee-Dae ;
Park, Kyu-Young ;
Song, Hyelynn ;
Jang, Eui Yun ;
Gwon, Hyeokjo ;
Kim, Jinsoo ;
Kim, Yong Hyup ;
Lima, Marcio D. ;
Robles, Raquel Ovalle ;
Lepro, Xavier ;
Baughman, Ray H. ;
Kang, Kisuk .
ADVANCED MATERIALS, 2013, 25 (09) :1348-1352
[15]   Nanosize effect on high-rate Li-ion intercalation in LiCoO2 electrode [J].
Okubo, Masashi ;
Hosono, Eiji ;
Kim, Jedeok ;
Enomoto, Masaya ;
Kojima, Norimichi ;
Kudo, Tetsuichi ;
Zhou, Haoshen ;
Honma, Itaru .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (23) :7444-7452
[16]   A Reversible and Higher-Rate Li-O2 Battery [J].
Peng, Zhangquan ;
Freunberger, Stefan A. ;
Chen, Yuhui ;
Bruce, Peter G. .
SCIENCE, 2012, 337 (6094) :563-566
[17]   Synthesis and electrochemical performance of high voltage cycling LiCo0.8M0.2O2 (M = Mg, Ca, Ba) as cathode material [J].
Sathiyamoorthi, R. ;
Chandrasekaran, R. ;
Gopalan, A. ;
Vasudevan, T. .
MATERIALS RESEARCH BULLETIN, 2008, 43 (06) :1401-1411
[18]   LiNi0.5+δMn0.5-δO2 -: A high-rate, high-capacity cathode for lithium rechargeable batteries [J].
Schougaard, SB ;
Bréger, J ;
Jiang, M ;
Grey, CP ;
Goodenough, JB .
ADVANCED MATERIALS, 2006, 18 (07) :905-+
[19]   Preparation and electrochemical performance of ball-like LiMn0.4Ni0.4Co0.2O2 cathode materials [J].
Shi, S. J. ;
Mai, Y. J. ;
Tang, Y. Y. ;
Cu, C. D. ;
Wang, X. L. ;
Tu, J. P. .
ELECTROCHIMICA ACTA, 2012, 77 :39-46
[20]   Sodium-Ion Batteries [J].
Slater, Michael D. ;
Kim, Donghan ;
Lee, Eungje ;
Johnson, Christopher S. .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (08) :947-958