Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2006

被引:26
作者
Edelmann, Frank T. [1 ]
机构
[1] Univ Magdeburg, Inst Chem, D-39106 Magdeburg, Germany
关键词
Lanthanides; Actinides; Cyclopentadienyl complexes; Cyclooctatetraenyl complexes; Organometallic chemistry; DENSITY-FUNCTIONAL-THEORY; H BOND ACTIVATION; METAL-CARBIDE ENDOFULLERENE; N-HETEROCYCLIC CARBENES; ATOMIC LAYER DEPOSITION; RARE-EARTH-METALS; X-RAY-DIFFRACTION; THIN-FILMS; STRUCTURAL-CHARACTERIZATION; ELECTRONIC-STRUCTURE;
D O I
10.1016/j.ccr.2008.03.003
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This review summarizes the progress in organo-f-element chemistry during the year 2006. A continuing trend in organolanthanide research is a strong emphasis on applications of organolanthanide complexes in homogeneous catalysis and, to a lesser extent, materials science. Only little more than 10% of all relevant papers published in 2006 were in the area of organoactinide chemistry, although the latter has produced some truly spectacular results. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:343 / 409
页数:67
相关论文
共 139 条
[51]   13C NMR spectroscopic study of scandium dimetallofullerene, Sc2@C84 vs. Sc2C2@ C82 [J].
Iiduka, Y ;
Wakahara, T ;
Nakajima, K ;
Tsuchiya, T ;
Nakahodo, T ;
Maeda, Y ;
Akasaka, T ;
Mizorogi, N ;
Nagase, S .
CHEMICAL COMMUNICATIONS, 2006, (19) :2057-2059
[52]   Synthesis of a new stable, neutral organothulium(II) complex by reduction of a thulium(III) precursor [J].
Jaroschik, F ;
Nief, F ;
Ricard, L .
CHEMICAL COMMUNICATIONS, 2006, (04) :426-428
[53]   Infrared spectroscopic and density functional theory studies on the CO dissociation by scandium and yttrium dimers [J].
Jiang, Ling ;
Xu, Qiang .
JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (17) :5636-5641
[54]   Reactions of gadolinium atoms and dimers with CO: Formation of gadolinium carbonyls and photoconversion to CO activated molecules [J].
Jin, Xi ;
Jiang, Ling ;
Xu, Qiang ;
Zhou, Mingfei .
JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (46) :12585-12591
[55]   Butadiene polymerization catalyzed by lanthanide metallocene-alkylaluminum complexes with cocatalysts: Metal-dependent control of 1,4-cis/trans stereoselectivity and molecular weight [J].
Kaita, S ;
Yamanaka, M ;
Horiuchi, AC ;
Wakatsuki, Y .
MACROMOLECULES, 2006, 39 (04) :1359-1363
[56]  
Kim BY, 2006, J KOREAN PHYS SOC, V49, P1303
[57]  
Kiplinger J. L., 2006, ANGEW CHEM, V118, P2090
[58]   Actinide-mediated cyclization of 1,2,4,5-tetracyanobenzene: Synthesis and characterization of self-assembled trinuclear thorium and uranium macrocycles [J].
Kiplinger, JL ;
Pool, JA ;
Schelter, EJ ;
Thompson, JD ;
Scott, BL ;
Morris, DE .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (13) :2036-2041
[59]   β-Diketiminato scandium chemistry:: Attempted deprotonation of cationic amido complexes [J].
Knight, Lisa K. ;
Piers, Warren E. ;
McDonald, Robert .
ORGANOMETALLICS, 2006, 25 (13) :3289-3292
[60]   Surface morphology of ErP layers on InP and Ga0.52In0.48P [J].
Koizumi, Atsushi ;
Ohnishi, Hiroyuki ;
Inoue, Tomohiro ;
Yamauchi, Takeshi ;
Yamakawa, Ichirou ;
Ofuchi, Hironori ;
Tabuchi, Masao ;
Nakamura, Arao ;
Takeda, Yoshikazu .
THIN SOLID FILMS, 2006, 515 (02) :543-546