Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2006

被引:26
作者
Edelmann, Frank T. [1 ]
机构
[1] Univ Magdeburg, Inst Chem, D-39106 Magdeburg, Germany
关键词
Lanthanides; Actinides; Cyclopentadienyl complexes; Cyclooctatetraenyl complexes; Organometallic chemistry; DENSITY-FUNCTIONAL-THEORY; H BOND ACTIVATION; METAL-CARBIDE ENDOFULLERENE; N-HETEROCYCLIC CARBENES; ATOMIC LAYER DEPOSITION; RARE-EARTH-METALS; X-RAY-DIFFRACTION; THIN-FILMS; STRUCTURAL-CHARACTERIZATION; ELECTRONIC-STRUCTURE;
D O I
10.1016/j.ccr.2008.03.003
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This review summarizes the progress in organo-f-element chemistry during the year 2006. A continuing trend in organolanthanide research is a strong emphasis on applications of organolanthanide complexes in homogeneous catalysis and, to a lesser extent, materials science. Only little more than 10% of all relevant papers published in 2006 were in the area of organoactinide chemistry, although the latter has produced some truly spectacular results. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:343 / 409
页数:67
相关论文
共 139 条
[1]   Formation of a dicationic yttrium η2-pyridyl complex from an yttrium methyl dication by C-H activation of pyridine [J].
Arndt, S ;
Elvidge, BR ;
Zeimentz, PM ;
Spaniol, TP ;
Okuda, J .
ORGANOMETALLICS, 2006, 25 (03) :793-795
[2]   Deprotonation of N-heterocyclic carbenes to afford heterobimetallic organolanthanide complexes [J].
Arnold, PL ;
Liddle, ST .
ORGANOMETALLICS, 2006, 25 (06) :1485-1491
[3]   Ring opening and C-O and C-N bond cleavage by transient reduced thorium species [J].
Arunachalampillai, Athimoolam ;
Crewdson, Patrick ;
Korobkov, Ilia ;
Gambarotta, Sandro .
ORGANOMETALLICS, 2006, 25 (16) :3856-3866
[4]   Synthesis, structure, and dynamics of tris(η5-cyclopentadienyl)lanthanides and bis(η5-cyclopentadienyl)[bis(trimethylsilyl)amido]cerium(III) [J].
Baisch, Ulrich ;
Pagano, Sandro ;
Zeuner, Martin ;
Gunne, Joern Schmedt auf der ;
Oeckler, Oliver ;
Schnick, Wolfgang .
ORGANOMETALLICS, 2006, 25 (12) :3027-3033
[5]   Nanocrystalline lanthanide nitride materials synthesised by thermal treatment of amido and ammine metallocenes: X-ray studies and DFT calculations [J].
Baisch, Ulrich ;
Zeuner, Martin ;
Barros, Noemi ;
Maron, Laurent ;
Schnick, Wolfgang .
CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (18) :4785-4798
[6]   Reactions of group 3 transition metal atoms with CS2 and OCS:: Matrix isolation infrared spectra and density-functional calculations of SMCS, SM-(η2-CS), SMCO, and SM-(η2-CO) in solid argon [J].
Baker, Alexander B. ;
Andrews, Lester .
JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (35) :10419-10426
[7]  
Bambirra S, 2006, DALTON T, P1157, DOI 10.1039/b512135c
[8]   Cationic group 3 alkyl complexes with isopropyl-substituted triazacyclononane-amide ligands: Synthesis, structure, and thermal decomposition processes [J].
Bambirra, Sergio ;
Meetsma, Auke ;
Hessen, Bart ;
Bruins, Andries P. .
ORGANOMETALLICS, 2006, 25 (14) :3486-3495
[9]   Lanthanum tribenzyl complexes as convenient starting materials for organolanthanum chemistry [J].
Bambirra, Sergio ;
Meetsma, Auke ;
Hessen, Bart .
ORGANOMETALLICS, 2006, 25 (14) :3454-3462
[10]   Surprising activity of organoactinide complexes in the polymerization of cyclic mono- and diesters [J].
Barnea, E ;
Moradove, D ;
Berthet, JC ;
Ephritikhine, M ;
Eisen, MS .
ORGANOMETALLICS, 2006, 25 (02) :320-322