Cobalt-catalyzed Branched-selective Addition of Aromatic Ketimines to Styrenes under Room-temperature Conditions

被引：41

作者：

Dong, Jinghua ^{[1
]}

Lee, Pin-Sheng ^{[1
]}

Yoshikai, Naohiko ^{[1
]}

机构：

[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore

来源：

CHEMISTRY LETTERS | 2013年 / 42卷 / 10期

基金：

新加坡国家研究基金会;

关键词：

C-H BOND; CARBON-HYDROGEN BONDS; ORTHO-ALKYLATION; HYDROARYLATION; ACTIVATION; EFFICIENT; ALKENES; ALKYNES; IMINES; ARENES;

D O I：

10.1246/cl.130508

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An improved cobalt-based catalytic system has been developed for the branched-selective addition of aromatic ketimines to styrenes. With an appropriate combination of triarylphosphine and the Grignard reagent, the reaction takes place smoothly at room temperature to afford 1,1-diarylethane derivatives with high regioselectivity.

引用

页码：1140 / 1142

页数：3

共 44 条

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