Synthesis, Structures, and Photoluminescent Properties of Cyclometalated Platinum(II) Complexes bearing Upper-Rim Phosphinated Calix[4]arenes

被引：20

作者：

Lai, Siu-Wai ^{[1
]}

Chan, Queenie K. -W.

Han, Jie

Zhi, Yong-Gang

Zhu, Nianyong

Che, Chi-Ming

机构：

[1] Univ Hong Kong, Inst Mol Technol Drug Discovery & Synth, Dept Chem, HKU CAS Joint Lab New Mat, Hong Kong, Hong Kong, Peoples R China

来源：

ORGANOMETALLICS | 2009年 / 28卷 / 01期

基金：

中国国家自然科学基金;

关键词：

ANION RECOGNITION PROPERTIES; RECEPTOR MOLECULES; LUMINESCENT; RUTHENIUM(II); LIGANDS; BIPYRIDYL; BINDING; CAVITY; FUNCTIONALIZATION; COBALTOCENIUM;

D O I：

10.1021/om800969z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of upper-rim diphosphinated calixarene receptors bearing various R and R' substituents at the lower riin (L-n; n = 1-5) were synthesized, and their reactions with [Pt(Thpy)(HThpy)Cl] afforded the phosphorescent platinum(II)modified calixarene receptors [(PtThpyCl)(2)L-n]. The structure of [[PtThpy(CH3CN)](2)L-1](ClO4)(2) and [(PtThpvCl)(2)L-5] were determined by X-ray crystallographic analysis, and the photophysical properties of [(PtThpyCl)(2)L-n] were investigated.

引用

页码：34 / 37

页数：4

共 28 条

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