Design of Novel Poly(ionic liquids) for the Conversion of CO2 to Cyclic Carbonates under Mild Conditions without Solvent

被引：111

作者：

Song, Hongbing ^{[1
]}

Wang, Yongjie ^{[1
]}

Xiao, Meng ^{[1
]}

Liu, Lei ^{[1
]}

Liu, Yule ^{[1
]}

Liu, Xiaofeng ^{[1
]}

Gai, Hengjun ^{[1
]}

机构：

[1] Qingdao Univ Sci & Technol, State Key Lab Base Ecochem Engn, Coll Chem Engn, Zhengzhou Rd 53, Qingdao 266042, Shandong, Peoples R China

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2019年 / 7卷 / 10期

基金：

中国国家自然科学基金; 国家重点研发计划;

关键词：

Ionic liquid; Poly(ionic liquids); Carbon dioxide; Heterogeneous catalysis; METAL-ORGANIC FRAMEWORK; IONIC LIQUIDS; SYNERGISTIC CATALYSTS; CHEMICAL FIXATION; HIGHLY EFFICIENT; SALEN COMPLEXES; CYCLOADDITION; EPOXIDES; POLYMERS; DIOXIDE;

D O I：

10.1021/acssuschemeng.9b00865

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The production of carbonates from carbon dioxide (CO2) and epoxides is an atom-economical reaction. This study developed a series of poly(ionic liquids) (PILs) by copolymerizing a novel functional ionic liquid (ethyl ether bis(1-vinylimidazolium) chloride) with ethylene glycol dime thacrylate (EGDMA). The structures and morphologies of PILs were investigated by adjusting the mole ratio between IL and EGDMA in the PILs. The prepared PILs were investigated as catalysts for the cycloaddition of CO2 with epoxides, and they show improved catalytic efficiency and accelerated mass transfer rate due to their mesoporous structure with a large number of uniformly distributed active ion sites. The PIL was stable, and the activity remained unchanged during the recycling of CO2 cycloaddition to epoxides under mild conditions without any solvent and co-catalyst. This study emphasizes the PIL as a versatile platform to obtain cyclic carbonates from CO2 under mild conditions.

引用

页码：9489 / 9497

页数：17

共 42 条

[1] Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation [J].

Appel, Aaron M. ;

Bercaw, John E. ;

Bocarsly, Andrew B. ;

Dobbek, Holger ;

DuBois, Daniel L. ;

Dupuis, Michel ;

Ferry, James G. ;

Fujita, Etsuko ;

Hille, Russ ;

Kenis, Paul J. A. ;

Kerfeld, Cheal A. ;

Morris, Robert H. ;

Peden, Charles H. F. ;

Portis, Archie R. ;

Ragsdale, Stephen W. ;

Rauchfuss, Thomas B. ;

Reek, Joost N. H. ;

Seefeldt, Lance C. ;

Thauer, Rudolf K. ;

Waldrop, Grover L. .

CHEMICAL REVIEWS, 2013, 113 (08) :6621-6658

[2] Synthesis of carbonates and related compounds incorporating CO2 using ionic liquid-type catalysts: State-of-the-art and beyond [J].

Bobbink, Felix D. ;

Dyson, Paul J. .

JOURNAL OF CATALYSIS, 2016, 343 :52-61

[3] Porous cationic polymers: the impact of counteranions and charges on CO2 capture and conversion [J].

Buyukcakir, Onur ;

Je, Sang Hyun ;

Choi, Dong Shin ;

Talapaneni, Siddulu Naiudu ;

Seo, Yongbeom ;

Jung, Yousung ;

Polychronopoulou, Kyriaki ;

Coskun, Ali .

CHEMICAL COMMUNICATIONS, 2016, 52 (05) :934-937

[4] Charged Metalloporphyrin Polymers for Cooperative Synthesis of Cyclic Carbonates from CO2 under Ambient Conditions [J].

Chen, Yaju ;

Luo, Rongchang ;

Xu, Qihang ;

Jiang, Jun ;

Zhou, Xiantai ;

Ji, Hongbing .

CHEMSUSCHEM, 2017, 10 (11) :2534-2541

[5] Effect of hydrogen bond of hydroxyl-functionalized ammonium ionic liquids on cycloaddition of CO2 [J].

Cheng, Weiguo ;

Xiao, Benneng ;

Sun, Jian ;

Dong, Kun ;

Zhang, Peng ;

Zhang, Suojiang ;

Ng, Flora T. T. .

TETRAHEDRON LETTERS, 2015, 56 (11) :1416-1419

[6] Synthesis of ordered mesoporous bifunctional TiO2-SiO2-polymer nanocomposites [J].

Chu, HuaQin ;

Yu, Chao ;

Wan, Ying ;

Zhao, Dongyuan .

JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (45) :8610-8618

[7] Salen-Complex-Mediated Formation of Cyclic Carbonates by Cycloaddition of CO2 to Epoxides [J].

Decortes, Antonello ;

Castilla, Ana M. ;

Kleij, Arjan W. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (51) :9822-9837

[8] Thiol-Functionalized Zr-Based Metal-Organic Framework for Capture of Hg(II) through a Proton Exchange Reaction [J].

Ding, Lin ;

Luo, Xubiao ;

Shao, Penghui ;

Yang, Jiakuan ;

Sung, Dongqi .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (07) :8494-8502

[9] Bifunctional Porphyrin Catalysts for the Synthesis of Cyclic Carbonates from Epoxides and CO2: Structural Optimization and Mechanistic Study [J].

Ema, Tadashi ;

Miyazaki, Yuki ;

Shimonishi, Junta ;

Maeda, Chihiro ;

Hasegawa, Jun-ya .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (43) :15270-15279

[10] Ionic Liquid-Catalyzed C-S Bond Construction using CO2 as a C1 Building Block under Mild Conditions: A Metal-Free Route to Synthesis of Benzothiazoles [J].

Gao, Xiang ;

Yu, Bo ;

Yang, Zhenzhen ;

Zhao, Yanfei ;

Zhang, Honge ;

Hao, Leiduan ;

Han, Buxing ;

Liu, Zhimin .

ACS CATALYSIS, 2015, 5 (11) :6648-6652

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