Metastable one-dimensional AgCl1-xIx solid-solution wurzite "tunnel" crystals formed within single-walled carbon nanotubes

被引：63

作者：

Sloan, J

Terrones, M

Nufer, S

Friedrichs, S

Bailey, SR

Woo, HG

Rühle, M

Hutchison, JL

Green, MLH

机构：

[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

[2] Univ Oxford, Dept Mat, Oxford OX1 3PH, England

[3] Max Planck Inst Met Res, D-70174 Stuttgart, Germany

[4] Chonnam Natl Univ, Dept Chem, Kwangju 500757, South Korea

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 10期

关键词：

D O I：

10.1021/ja0173270

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High-resolution transmission electron microscopy and spatially resolved electron loss spectroscopy have revealed that a eutectic mixture of AgCl and AgI crystallizes within single walled carbon nanotubes (SWNTs) as metastable AgCl1-xIx 1D solid solution crystals. The incorporated halide crystals form wurzite "tunnel" structures with locally varying Cl:I ratios and reduced Ag coordination. Copyright © 2002 American Chemical Society.

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页码：2116 / 2117

页数：2

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