Syntheses and crystal structures of cobalt(II) chloride complexes of 1,3-bis(pyridyl-4-ylthio)propan-2-one

被引：0
|
作者：
Wu Ben-Lai [1 ]
Wu Ming-Yan [1 ]
Gong Ya-Qiong [1 ]
Chen Bai-Quan [1 ]
Hong Mao-Chun [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2006年 / 25卷 / 05期
关键词：
cobalt chloride complex; 1,3-bis(pyridyl-4-ylthio)propan-2-one; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of 1,3-bis(pyridyl-4-ylthio)propan-2-one L and CoCl(2)(.)6H(2)O under different conditions gave two new cobalt(II)-chloride-L complexes with distinct structures. Complex [Co(L)(2)Cl-2](.)0.5CH(3)OH}n 1 prepared by solvothermal treatment is a 3D network, whereas complex [Co-3(L)(2)Cl-6(DMF)4](.)2CH(3)OH(.)H(2)O} 2 obtained in DMF-diethyl ether system is a discrete acyclic trimer. Crystal data for 1: space group Ibca, a = 15.993(4), b = 18.454(5), c = 21.506(6) angstrom, V = 6347(3) angstrom(3), Z = 8, D-c = 1.462 g/cm(3), mu = 1.005 mm(-1), F(000) = 2864, C26.5H26Cl2CoN4O2.5S4, M-r = 698.58, the final R = 0.0499 and wR = 0.1024. Crystal data for 2: space group P (1) over bar, a = 9.9177(6), b = 11.0871(4), c = 15.5490(12) angstrom, alpha = 83.1834(14), beta = 88.910(13), gamma = 71.096(11)degrees, V = 1605.8(2) angstrom(3), Z = 1, D-c = 1.362 g/cm(3), mu = 1.194 mm(-1), F(000) = 677, C40H62Cl6Co3N8O9S4, M-r = 1316.71, the final R = 0.0666 and wR = 0.1575.
引用
收藏
页码：511 / 516
页数：6
相关论文
共 50 条
  • [21] Syntheses, Crystal Structures and Catalytic Performance of 2,6-Bis(imino) pyridyl Manganese Complexes
    Fan Rui-Qing
    Yuan Guo-Hui
    Ding Xiao-Dong
    Chen Jie
    Yang Yu-Lin
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2011, 32 (06): : 1239 - 1243
  • [22] Reaction and crystal structures of 1,3-bis(trimethylsilyl)-2-t-butyl-aza-allyl-lithium with iron(II), cobalt(II), nickel(II), titanium(IV)
    Zhang Yong
    Guo Jian-Ping
    Tong Hong-Bo
    Huang Shu-Ping
    Liu Dian-Sheng
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2006, 22 (07) : 1175 - 1179
  • [23] Syntheses, Crystal Structures of Two Cobalt(II)/Zinc(II) Complexes Based on Bis(4-(pyridin-4-yl)phenyl)amine
    Zhang Chun-Li
    Zheng He-Gen
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2016, 32 (04) : 706 - 712
  • [24] Transition metal complexes with squarate anion and the pyridyl-donor ligand 1,3-bis(4,-pyridyl)propane (BPP):: Synthesis, crystal structure and spectroscopic investigation
    Correa, Charlane C.
    Diniz, Renata
    Chagas, Luciano H.
    Rodrigues, Bernardo L.
    Yoshida, Maria I.
    Teles, Wagner M.
    Machado, Flavia C.
    de Oliveira, Luiz Fernando C.
    POLYHEDRON, 2007, 26 (05) : 989 - 995
  • [25] Syntheses and crystal structures of N,N-bis(2-aminoethyl)-1,3-propyl diamine complexes with nickel (II)
    Zhu, HL
    Bu, WM
    Tang, WX
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 1999, 15 (04) : 423 - 428
  • [26] Syntheses and crystal structures of cobalt and nickel complexes of 2,6-bis(hydroxymethyl)pyridine
    Winter, S
    Seichter, W
    Weber, E
    JOURNAL OF COORDINATION CHEMISTRY, 2004, 57 (12) : 997 - 1014
  • [27] Coordination versatility of 1,3-bis[3-(2-pyridyl)pyrazol-1-yl]propane: Co(II) and Ni(II) complexes
    Mishra, Vibha
    Lloret, Francesc
    Mukherjee, Rabindranath
    INORGANICA CHIMICA ACTA, 2006, 359 (12) : 4053 - 4062
  • [28] Supramolecular structures of Mn2+, Co2+ and Zn2+ complexes containing 1,3-bis(4-pyridyl)propane and aminosalicylate anion
    Garcia, Humberto C.
    Chagas, Luciano H.
    Diniz, Renata
    de Oliveira, Luiz Fernando C.
    SUPRAMOLECULAR CHEMISTRY, 2013, 25 (08) : 503 - 511
  • [29] Synthesis, vibrational spectroscopy and crystal structures of polymers involving transition metals with squarate ions and 1,3-bis(4-pyridyl)propane
    Correa, Charlane C.
    Diniz, Renata
    Chagas, Luciano H.
    Rodrigues, Bernardo L.
    Yoshida, Maria I.
    Teles, Wagner M.
    Machado, Flavia C.
    Edwards, Howell G. M.
    de Oliveira, Luiz Fernando C.
    VIBRATIONAL SPECTROSCOPY, 2007, 45 (02) : 82 - 88
  • [30] Synthesis, Topological Analysis, and Magnetic Properties of one Manganese(II) Coordination Polymer With Acetylenedicarboxylato and 1,3-Bis(4-pyridyl)-propane
    Zhu, Hong-Lin
    Lin, Jian-Li
    Liu, Ji-Yong
    Zheng, Yue-Qing
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2013, 43 (09) : 1190 - 1196
12345