A Resol-Assisted Co-Assembly Approach to Crystalline Mesoporous Niobia Spheres for Electrochemical Biosensing

被引：83

作者：

Luo, Wei ^{[1
]}

Li, Yuhui ^{[1
]}

Dong, Junping ^{[2
]}

Wei, Jing ^{[1
]}

Xu, Jiaqiang ^{[2
]}

Deng, Yonghui ^{[1
]}

Zhao, Dongyuan ^{[1
]}

机构：

[1] Fudan Univ, Adv Mat Lab, Dept Chem, Shanghai 200433, Peoples R China

[2] Shanghai Univ, Coll Sci, Dept Chem, Shanghai 200444, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 40期

基金：

高等学校博士学科点专项科研基金;

关键词：

biosensor; block copolymers; mesoporous materials; niobium; resol; METAL-OXIDES; DIBLOCK COPOLYMER; MOLECULAR-SIEVE; THIN-FILMS; SILICA; NANOPARTICLES; MICROSPHERES; SHELL; CORE; NANOCOMPOSITES;

D O I：

10.1002/anie.201303353

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Templated pores: A resol-assisted solvent-evaporation-induced self-assembly (RA-EISA) gives unique ordered mesoporous niobia spheres by using the amphiphilic diblock copolymer PEO-b-PS as a template. The mesoporous Nb 2O5 spheres have ordered hexagonal structures, large pore size and high surface area, and a nanocrystalline framework (see picture). They show excellent electrochemical sensing of hydrogen peroxide. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10505 / 10510

页数：6

共 23 条

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