Ethylene/allyl monomer cooligomerization by nickel/phosphine-sulfonate catalysts

被引:68
作者
Ito, Shingo [1 ]
Ota, Yusuke [1 ]
Nozaki, Kyoko [1 ]
机构
[1] Univ Tokyo, Dept Chem & Biotechnol, Grad Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan
关键词
POLAR VINYL MONOMERS; OLEFIN POLYMERIZATION; COPOLYMERIZATION; COMPLEXES; LIGANDS; ACRYLONITRILE; POLYETHYLENE;
D O I
10.1039/c2dt31771k
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Nickel(II) complexes bearing a phosphine-sulfonate ligand, [(R2PC6H4SO3)NiMe(2,6-lutidine)] (R = cyclohexyl, 2-MeOC6H4, and 2-[2',6'-(MeO)(2)C6H3]C6H4, were synthesized and applied as catalysts for the cooligomerizations of ethylene and allyl monomers.
引用
收藏
页码:13807 / 13809
页数:3
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