Polynuclear palladium phosphide and phosphineidene complexes: Synthesis and properties as catalysts for hydrogenation

被引：0
|
作者：
Belykh, LB [1 ]
Cherenkova, TV [1 ]
Shmidt, FK [1 ]
机构：
[1] Irkutsk State Univ, Irkutsk 664033, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 1999年 / 25卷 / 06期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Interaction of palladium bis(acetylacetonate) with alkali-metal diphenyl- and phenylphosphides was studied. The reaction of Pd(Acac)(2) with NaPPh2 was found to proceed through the step of formation of a binuclear [Pd(Acac)(PPh2)](2) complex to yield sodium tris(diphenylphosphido)palladate as a final product. It was shown that the interaction of Pd(Acac)(2) with Li2PPh is accompanied by the side redox processes resulting in the phenylphosphineidene complexes [Pd-4(PPh)(3)](n). The latter exhibit high activity for hydrogenation of unsaturated hydrocarbons.
引用
收藏
页码：418 / 422
页数：5
相关论文
共 50 条
  • [1] Hydrogenation catalysts based on polynuclear palladium complexes with organophosphorus ligands
    Belykh, LB
    Goremyka, TV
    Rokhin, AV
    Belonogova, LN
    Shmidt, FK
    KINETICS AND CATALYSIS, 2004, 45 (03) : 385 - 390
  • [2] Hydrogenation Catalysts Based on Polynuclear Palladium Complexes with Organophosphorus Ligands
    L. B. Belykh
    T. V. Goremyka
    A. V. Rokhin
    L. N. Belonogova
    F. K. Shmidt
    Kinetics and Catalysis, 2004, 45 : 385 - 390
  • [3] Formation and properties of hydrogenation catalysts based on palladium complexes with primary phosphines
    Belykh, LB
    Goremyka, TV
    Gusarova, NK
    Sukhov, BG
    Shmidt, FK
    KINETICS AND CATALYSIS, 2005, 46 (04) : 572 - 577
  • [4] Formation and Properties of Hydrogenation Catalysts Based on Palladium Complexes with Primary Phosphines
    L. B. Belykh
    T. V. Goremyka
    N. K. Gusarova
    B. G. Sukhov
    F. K. Shmidt
    Kinetics and Catalysis, 2005, 46 : 572 - 577
  • [5] Palladium phosphide nanoparticles as highly selective catalysts for the selective hydrogenation of acetylene
    Liu, Yanan
    McCue, Alan J.
    Miao, Chenglin
    Feng, Junting
    Li, Dianqing
    Anderson, James A.
    JOURNAL OF CATALYSIS, 2018, 364 : 406 - 414
  • [6] HYDROGENATION CATALYSTS BASED ON PALLADIUM COMPLEXES WITH POLY(VINYLPYRIDINE)
    ZHARMAGAMBETOVA, AK
    MUKHAMEDZHANOVA, SG
    BEKTUROV, EA
    REACTIVE POLYMERS, 1994, 24 (01): : 17 - 20
  • [7] HYDROGENATION CATALYSTS BASED ON COMPLEXES OF PALLADIUM(II) AND POLYVINYLPYRIDINES
    ZHARMAGAMBETOVA, AK
    MUKHAMEDZHANOVA, SG
    BEKTUROV, EA
    SALTYKOV, YP
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1991, 64 (12): : 2382 - 2386
  • [8] Polymer supported palladium (II) complexes as hydrogenation catalysts
    Mukherjee, D
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2003, 42 (02): : 346 - 352
  • [9] SYNTHESIS AND CHARACTERIZATION OF NEW FERROCENYLAMINE SULFIDE LIGANDS AND THEIR PALLADIUM COMPLEXES AS CATALYSTS FOR SELECTIVE HYDROGENATION
    WANG, CH
    BRUBAKER, CH
    JOURNAL OF MOLECULAR CATALYSIS, 1992, 75 (03): : 221 - 233
  • [10] Synthesis, properties, and activity of nanosized palladium catalysts modified with elemental phosphorus for hydrogenation
    L. B. Belykh
    N. I. Skripov
    L. N. Belonogova
    V. A. Umanets
    F. K. Schmidt
    Kinetics and Catalysis, 2010, 51 : 42 - 49
12345