Suppression of the lithium-ion battery thermal runaway during quantitative-qualitative change

被引:1
作者
Tang, W. [1 ]
Xu, X. M. [1 ]
Li, R. Z. [1 ]
Jin, H. F. [2 ]
Cao, L. D. [2 ]
Wang, H. M. [2 ]
机构
[1] Jiangsu Univ, Sch Automot & Traff Engn, Zhenjiang 212013, Jiangsu, Peoples R China
[2] Tian Jin Li Shen Battery Joint Stock Co Ltd, Tianjin 300384, Peoples R China
基金
中国国家自然科学基金;
关键词
Lithium-ion battery; Thermal runaway suppression; Temperature distribution; Side reaction; Temperature rise; Heat generation; LINI1/3MN1/3CO1/3O2 CATHODE MATERIAL; HIGH-POWER; BEHAVIOR; MODEL; MANAGEMENT; SAFETY; CELLS; FIRE;
D O I
10.1007/s11581-020-03745-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thermal runaway is the most important safety problem of the lithium-ion battery. A thermal model-combined four side reactions is established to simulate suppression of the thermal runaway of a lithium-ion battery, and the effect of suppression starting time is analyzed to further reveal the thermal runaway suppression mechanism. The results show that thermal runaway is triggered by the heat generation of negative material reaction when it is heated with 473.15 K, and heat dissipation in the bottom part of negative electrode material at 293.15 K can effectively inhibit the occurrence of thermal runaway before solid electrolyte interface (SEI) decomposition reaction starts. In addition, the suppression of runaway battery heat is to suppress the negative electrode material reaction actually, and when the heat is dissipated at 293.15 K, it could be conducted before the SEI decomposition reaction starts, which has nothing to do with the advance time.
引用
收藏
页码:6133 / 6143
页数:11
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