Growth, thermal, spectroscopic, and optical studies of L-alaninium maleate, a new organic nonlinear optical material

被引:107
作者
Natarajan, S [1 ]
Britto, SAM
Ramachandran, E
机构
[1] Madurai Kamaraj Univ, Sch Phys, Madurai 625021, Tamil Nadu, India
[2] Thiruvalluvar Coll, Dept Phys, Papanasam 627425, Tamil Nadu, India
关键词
D O I
10.1021/cg0502439
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
L-Alaninium maleate (C3H8NO2+C4H3O4-), a new organic nonlinear optical (NLO) material, is synthesized. Optical behavior such as UV-visible-NIR absorption spectra and second harmonic generation (SHG) were investigated to explore the NLO characteristics of the material for the first time. Thermal analysis and Fourier transform infrared (FTIR) spectroscopic studies of the specimen were also conducted. Characterization of the crystals was made using single-crystal X-ray diffraction and density determinations.
引用
收藏
页码:137 / 140
页数:4
相关论文
共 21 条
[1]   L-Alaninium maleate [J].
Alagar, M ;
Krishnakumar, RV ;
Nandhini, MS ;
Natarajan, S .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2001, 57 :o855-o857
[2]  
BERNSTEIN HJ, 1962, SPECTROCHIM ACTA, V18, P161, DOI 10.1016/0371-1951(62)80032-0
[3]   GROWTH AND CHARACTERIZATION OF SOME NOVEL CRYSTALS FOR NONLINEAR-OPTICAL APPLICATIONS [J].
BHAT, HL .
BULLETIN OF MATERIALS SCIENCE, 1994, 17 (07) :1233-1249
[4]   Growth of nonlinear optical γ-glycine crystals [J].
Bhat, MN ;
Dharmaprakash, SM .
JOURNAL OF CRYSTAL GROWTH, 2002, 236 (1-3) :376-380
[5]   Spectroscopically-tested, improved, semi-empirical potentials for biological molecules: Calculations for glycine, alanine and proline [J].
Brauer, B ;
Chaban, GM ;
Gerber, RB .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (10) :2543-2556
[6]  
DELFINO M, 1979, MOL CRYST LIQ CRYST, V52, P575
[7]   Structural, thermal and optical characterizations of a NLO material: L-alaninium oxalate [J].
Dhanuskodi, S ;
Vasantha, K .
CRYSTAL RESEARCH AND TECHNOLOGY, 2004, 39 (03) :259-265
[8]  
Dmitriev V. G., 1999, Handbook of Nonlinear Optical Crystals
[9]  
DOWTY E, 2003, SHAPE VERSION 7 1
[10]   Carbamic acid: molecular structure and IR spectra [J].
Khanna, RK ;
Moore, MH .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1999, 55 (05) :961-967