Solvent-tuned azido-bridged Co2+ layers:: Square, honeycomb, and Kagome

被引：296
作者：
Wang, XY [1 ]
Wang, L [1 ]
Wang, ZM [1 ]
Gao, S [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Appl, Beijing 100871, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 03期
关键词：
D O I：
10.1021/ja055725n
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three azido-bridged Co2+ complexes with square, honeycomb, and Kagomé layered structures were synthesized and structurally characterized. Crystallization solvents are found to be critical in generating the observed topologies. These structurally related complexes are of significance in studying two-dimensional antiferromagnetism and geometric frustration. Copyright © 2006 American Chemical Society.
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页码：674 / 675
页数：2
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