Remarkable enhancement of reactivity of carbonyl compounds for polymerizations with non-activated aromatic hydrocarbons

被引：55

作者：

Zolotukhin, M

Fomine, S

Salcedo, R

Khalilov, L

机构：

[1] Univ Nacl Autonoma Mexico, Inst Invest Mat, Mexico City 04510, DF, Mexico

[2] Inst Oil Chem & Catalysis, Ufa 450054, Russia

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 08期

关键词：

D O I：

10.1039/b317108f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of carbonyl compounds bearing electron-withdrawing substituents with non-activated aromatic hydrocarbons proceeds selectively in trifluoromethanesulfonic acid (TFSA) at room temperature to give linear, high-molecular-weight polymers.

引用

页码：1030 / 1031

页数：2

共 9 条

[1] ELECTRONEGATIVELY SUBSTITUTED CARBOCATIONS [J].

CREARY, X .

CHEMICAL REVIEWS, 1991, 91 (08) :1625-1678

[2] ELECTRON-DEFICIENT CARBOCATIONS [J].

GASSMAN, PG ;

TIDWELL, TT .

ACCOUNTS OF CHEMICAL RESEARCH, 1983, 16 (08) :279-285

[3]

Klumpp DA, 2001, RRD ORG CHEM, V5, P193

[4] SYNTHESIS OF MULTIFUNCTIONAL TRIARYLFLUOROETHANES .1. CONDENSATION OF FLUORO KETONES [J].

KRAY, WD ;

ROSSER, RW .

JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (07) :1186-1189

[5]

MARCH J, 1992, ADV ORG CHEM, P548

[6] SUPERELECTROPHILES [J].

OLAH, GA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (06) :767-788

[7]

OLAH GA, 1964, FRIEDEL CRAFTS RELAT, V2, P597

[8]

*SCHROD INC, 2000, JAG 4 2

[9] DESTABILIZED CARBOCATIONS [J].

TIDWELL, TT .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (01) :20-32

← 1 →