Carbocatalysis in Liquid-Phase Reactions

被引：223

作者：

Su, Dang Sheng ^{[1
]}

Wen, Guodong ^{[1
]}

Wu, Shuchang ^{[2
]}

Peng, Feng ^{[3
]}

Schloegl, Robert ^{[2
,4
]}

机构：

[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China

[2] Max Planck Inst Chem Energiekonvers, Stiftstr 34-36, D-45470 Mulheim, Germany

[3] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China

[4] Fritz Haber Inst Max Planck Gesell, Faradayweg 4-6, D-14195 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 04期

基金：

中国国家自然科学基金;

关键词：

active sites; carbocatalysis; liquid phase; nanocarbon materials; reaction mechanisms; SELECTIVE AEROBIC OXIDATION; METAL-FREE CATALYST; GRAPHITIC CARBON NITRIDE; MODIFIED ANNEALED NANODIAMOND; ORDERED MESOPOROUS CARBON; SOLID BASE CATALYSTS; ONE-STEP SYNTHESIS; WET AIR OXIDATION; GRAPHENE OXIDE; HIGHLY EFFICIENT;

D O I：

10.1002/anie.201600906

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

There is broad interest in metal-free catalysis for sustainable chemistry. Carbocatalysis is a "green" option for catalytic transformations in the gas phase as well as in the liquid phase. This is evident by the numerous reports on gas-phase dehydrogenation and selective oxidation where carbon can be used as a successful alternative to metal oxide systems. Carbocatalysis for liquid-phase reactions, especially for organic synthesis, is an emerging research discipline and has undergone rapid development in recent years. This Review provides a critical analysis on the state-of-the-art of carbocatalysts for liquid-phase reactions, with a focus on the underlying mechanisms as well as the advantages and limitations of metal-free carbocatalysts.

引用

页码：936 / 964

页数：29

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