Carbocatalysis in Liquid-Phase Reactions

被引:220
作者
Su, Dang Sheng [1 ]
Wen, Guodong [1 ]
Wu, Shuchang [2 ]
Peng, Feng [3 ]
Schloegl, Robert [2 ,4 ]
机构
[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China
[2] Max Planck Inst Chem Energiekonvers, Stiftstr 34-36, D-45470 Mulheim, Germany
[3] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
[4] Fritz Haber Inst Max Planck Gesell, Faradayweg 4-6, D-14195 Berlin, Germany
基金
中国国家自然科学基金;
关键词
active sites; carbocatalysis; liquid phase; nanocarbon materials; reaction mechanisms; SELECTIVE AEROBIC OXIDATION; METAL-FREE CATALYST; GRAPHITIC CARBON NITRIDE; MODIFIED ANNEALED NANODIAMOND; ORDERED MESOPOROUS CARBON; SOLID BASE CATALYSTS; ONE-STEP SYNTHESIS; WET AIR OXIDATION; GRAPHENE OXIDE; HIGHLY EFFICIENT;
D O I
10.1002/anie.201600906
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
There is broad interest in metal-free catalysis for sustainable chemistry. Carbocatalysis is a "green" option for catalytic transformations in the gas phase as well as in the liquid phase. This is evident by the numerous reports on gas-phase dehydrogenation and selective oxidation where carbon can be used as a successful alternative to metal oxide systems. Carbocatalysis for liquid-phase reactions, especially for organic synthesis, is an emerging research discipline and has undergone rapid development in recent years. This Review provides a critical analysis on the state-of-the-art of carbocatalysts for liquid-phase reactions, with a focus on the underlying mechanisms as well as the advantages and limitations of metal-free carbocatalysts.
引用
收藏
页码:936 / 964
页数:29
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