Watson-Crick base-pairing properties of nucleic acid analogues with stereocontrolled a and torsion angles (α,β-D-CNAs)

被引：37

作者：

Dupouy, Christelle ^{[1
]}

Iche-Tarrat, Nathalie ^{[1
]}

Durrieu, Marie-Pierre ^{[1
]}

Rodriguez, Frederic ^{[1
]}

Escudier, Jean-Marc ^{[1
]}

Vigroux, Alain ^{[1
]}

机构：

[1] Univ Toulouse 3, CNRS, UMR 5068, Lab Synth & Physicochim Mol Interet Biol, F-31062 Toulouse 9, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 22期

关键词：

conformation analysis; DNA structures; helical structures; nucleic acids; oligonucleoticles;

D O I：

10.1002/anie.200504475

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Constrained nucleic acids (α,β-D-CNAs) have an ethylene bridge that locks the α and β backbone torsion angles of DNA in the canonical (gauche(-),trans) conformation, as in B-form DNA (see picture), or in the noncanonical (gauche(+),trans) conformation. Canonical α,β-D-CNAs enhance the duplex-forming ability of oligonucleotides with complementary DNA, while noncanonical α,β-D-CNAs stabilize distorted B-DNA structures. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3623 / 3627

页数：5

共 46 条

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