Iron Complexation Studies of Gallic Acid

被引：121

作者：

Fazary, Ahmed Eid ^{[1
]}

Taha, Mohamed ^{[1
]}

Ju, Yi-Hsu ^{[1
]}

机构：

[1] Natl Taiwan Univ Sci & Technol, Dept Chem Engn, Taipei 10607, Taiwan

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2009年 / 54卷 / 01期

关键词：

PHENOLIC-COMPOUNDS; FERRIC IONS; PROTONATION EQUILIBRIA; ANTIOXIDANT ACTIVITY; LIGAND-EXCHANGE; AMINO-ACIDS; IRON(III); ABSORPTION; WATER; PH;

D O I：

10.1021/je800441u

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

In this work, formation in the binary and ternary systems of the Fe-III metal ion with gallic acid and glycine was investigated by means of potentiometry, conductometry, polarography, and UV-visible absorption spectroscopy techniques at 25 degrees C and in I = 0.10 mol center dot dm(-3) NaNO3. The protonation equilibria of gallic acid and glycine were investigated and discussed. The acidity constants of gallic acid and glycine were determined and used for determining the stability constants of the binary and ternary complexes formed in the aqueous medium under the experimental conditions. The ternary complex formation was found to occur in a stepwise manner. The stability constants of these binary and ternary systems were calculated. The concentration distribution of the various complex species in solution was evaluated and discussed. The solid binary [Fe-III-gallic acid] and ternary [Fe-III-gallic acid-glycine] complexes were synthesized and characterized by elemental analysis, FT-IR, H-1 NMR, and C-13 NMR spectroscopy.

引用

页码：35 / 42

页数：8

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