Synthesis of Ethyl tert-Butyl Ether in Packed Reactive Distillation Column Using Macroporous Ion Exchange Resin Catalyst

被引：0

作者：

Umar, Muhatttmad ^{[1
]}

Saleemi, Anwar R. ^{[2
]}

Feroz, Nadeem ^{[2
]}

Qaiser, Suleman ^{[2
]}

机构：

[1] Univ Engn & Technol, Lahore 54890, Pakistan

[2] Univ Engn & Technol, Dept Chem Engn, Lahore 54890, Pakistan

来源：

WCECS 2008: WORLD CONGRESS ON ENGINEERING AND COMPUTER SCIENCE | 2008年

关键词：

ETBE synthesis; ion exchange resin catalyst; packed column; reactive distillation;

D O I：

暂无

中图分类号：

TP39 [计算机的应用];

学科分类号：

081203 ; 0835 ;

摘要：

Liquid phase synthesis of one of the important fuel oxygenate, Ethyl tort-butyl ether (ETBE) from ethanol and tort-butyl alcohol (TBA) has been studied in reactive distillation column (RDC) using ion exchange resin catalyst CT-145H. A packed RDC was used to generate experimental data. Effect of different key variables on reactant conversion and product purity in distillate, was investigated to find the optimum operating conditions for ETBE synthesis. The optimum conditions found were; reboiler duty of 375 Watts, molar feed ratio of reactants, 1:1.3 and reflux ratio of seven. Concentration profiles for each component along the length of the column at optimum conditions were also drawn.

引用

页码：79 / 84

页数：6

共 50 条

[21] Dynamic simulation of startup in ethyl tert-butyl ether reactive distillation with input multiplicity
Bisowarno, BH
Tadé, MO
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (06) : 1950 - 1954
[22] Synthesis of ethyl tert-butyl ether on pellets cation exchange resins
Yang, Bolun
Yang, Sanba
Huagong Xuebao/Journal of Chemical Industry and Engineering (China), 2001, 52 (09): : 797 - 802
[23] KINETICS AND EFFECTIVENESS OF CATALYST FOR SYNTHESIS OF METHYL TERT-BUTYL ETHER IN CATALYTIC DISTILLATION
XU, X
ZHENG, YX
ZHENG, GW
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (07) : 2232 - 2236
[24] Kinetics and effectiveness of catalyst for synthesis of methyl tert-butyl ether in catalytic distillation
Tianjin Univ, Tianjin, China
Ind Eng Chem Res, 7 (2232-2236):
[25] Optimal design of reactive distillation systems: Application to the production of ethyl tert-butyl ether (ETBE)
Domingues, Luis
Pinheiro, Carla I. C.
Oliveira, Nuno M. C.
COMPUTERS & CHEMICAL ENGINEERING, 2014, 64 : 81 - 94
[26] Comparison of catalytic performances for the synthesis of ethyl tert-butyl ether using cation exchange resins
Yang, Bo-lun
Yang, Gao-wen
Yang, San-ba
Huaxue Fanying Gongcheng Yu Gongyi/Chemical Reaction Engineering and Technology, 2000, 16 (02): : 148 - 152
[27] LIQUID-PHASE SYNTHESIS OF METHYL TERT-BUTYL ETHER CATALYZED BY ION-EXCHANGE RESIN
SUBRAMANIAM, C
BHATIA, S
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1987, 65 (04): : 613 - 620
[28] KINETICS OF LIQUID-PHASE SYNTHESIS OF METHYL TERT-BUTYL ETHER FROM TERT-BUTYL ALCOHOL AND METHANOL CATALYZED BY ION-EXCHANGE RESIN
MATOUQ, MH
GOTO, S
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1993, 25 (10) : 825 - 831
[29] Thermodynamic Study of Liquid Phase Synthesis of Ethyl tert-Butyl Ether Using tert-Butyl Alcohol and Ethanol
Ozbay, Nalan
Oktar, Nuray
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (12): : 3208 - 3214
[30] Experimental study of the simultaneous synthesis of methyl tert-butyl ether and ethyl tert-butyl ether in liquid phase
Gomez, C
Cunill, F
Iborra, M
Izquierdo, F
Tejero, J
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1997, 36 (11) : 4756 - 4762

← 1 2 3 4 5 →