Amperometric sensor for hydrogen peroxide based on poly(aniline-co-p-aminophenol)

被引:41
作者
Chen, Chuanxiang [1 ,2 ]
Sun, Cheng [1 ]
Gao, Yuhua [2 ]
机构
[1] Nanjing Univ, Sch Environm, State Key Lab Pollut Control & Resource Reuse, Nanjing 210093, Peoples R China
[2] Jiangsu Univ Sci & Technol, Sch Mat Sci & Engn, Dept Chem, Zhenjiang 212003, Peoples R China
基金
中国国家自然科学基金;
关键词
Amperometric sensor; Electrocatalytic oxidation; Hydrogen peroxide; Poly(aniline-co-p-aminophenol); HORSERADISH-PEROXIDASE; NANOCOMPOSITE FILM; OPTICAL PROBE; ELECTRODE; IMMOBILIZATION;
D O I
10.1016/j.elecom.2008.12.026
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
It was found that the poly(aniline-co-p-aminophenol) film can effectively catalyze the oxidation of hydrogen peroxide in a sodium citrate buffer solution with pH 5.0. Here, we applied the copolymer to the construction of an efficient electrochemical sensor to determine the concentration of hydrogen peroxide. The sensor exhibited an excellent electrocatalytic activity toward the oxidation of H2O2, and the interferences of ascorbic acid and phenol were completely avoided. Unlike the inherent instability of enzyme, the poly(aniline-co-p-aminophenol) film-based sensor showed an outstanding stability. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:450 / 453
页数:4
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