Structure and bonding in metal sulfoxide complexes

被引：306
作者：
Calligaris, M [1 ]
Carugo, O [1 ]
机构：
[1] UNIV PAVIA,DIPARTIMENTO CHIM GEN,I-27100 PAVIA,ITALY
来源：
COORDINATION CHEMISTRY REVIEWS | 1996年 / 153卷
关键词：
metal sulphoxide complexes;
D O I：
10.1016/0010-8545(95)01193-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Structural parameters of free and coordinated sulfoxides are comprehensively reviewed and average values derived. Principal component analyses have been performed in order to evidence the deformation pathways of sulfoxides upon coordination. Electronic and steric factors affecting the bonding made of sulfoxides are discussed.
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页码：83 / 154
页数：72
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